阵列状金红石型TiO2的制备及晶体生长机理Fabrication and crystal growth mechanism of arrayed rutile type TiO2
王亚明,闫焉服,Osaka Akiyoshi,逯峙,王广欣,邓舜岚,宋艳春
摘要(Abstract):
采用催化氧化的方法以特殊的陶瓷粉体在α-Ti表面制备具有生物活性的阵列状二氧化钛薄膜。借助X射线衍射(XRD)、扫描电镜(SEM)、能谱分析(EDS)等手段对材料的相组成和微观形貌进行表征,探究四硼酸钠对薄膜制备工艺的影响以及阵列二氧化钛的晶体生长机理。结果表明:经四硼酸钠催化氧化后,纯钛表层的二氧化钛呈阵列状生长;该二氧化钛为沿(110)晶面生长的金红石相,同(002)晶面α-Ti均为拓扑生长结构;根据晶格匹配原理,(110)晶面金红石在(002)晶面ɑ-Ti上选择性生长;经此方法制备的二氧化钛薄膜粗糙度和表面积均有所增大,钛合金的生物相容性得到改善。
关键词(KeyWords): 催化氧化;阵列TiO2;拓扑生长;晶格匹配
基金项目(Foundation): 国家02重大专项支持(2017ZX02408003)
作者(Author): 王亚明,闫焉服,Osaka Akiyoshi,逯峙,王广欣,邓舜岚,宋艳春
DOI: 10.13289/j.issn.1009-6264.2017-0521
参考文献(References):
- [1]Cao H,Liu X.Activating titanium oxide coatings for orthopedic implants[J].Surface&Coatings Technology,2013,233(43):57-64.
- [2]Zhang E,Li F,Wang H.A new antibacterial titanium-copper sintered alloy:Preparation and antibacterial property[J].Materials Science&Engineering C Materials for Biological Applications,2013,33(7):4280-4287.
- [3]Mei S,Wang H,Wang W.Antibacterial effects and biocompatibility of titanium surfaces with graded silver incorporation in titania nanotubes[J].Biomaterials,2014,35(14):4255-4265.
- [4]Wang Y P,Li F,Wang H,et al.Osteogenic potential of a novel microarc oxidized coating formed on Ti6Al4V alloys[J].Applied Surface Science,2017,412:29-36.
- [5]Geetha M,Singh A K,Asokamani R,et al.Ti based biomaterials,the ultimate choice for orthopaedic implants-A review[J].Progress in Materials Science,2009,54:397-425.
- [6]Damodaran V B,Bhatnagar D,Leszczak V.Titania nanostructures:a biomedical perspective[J].Rsc Advances,2015,5(47):37149-37171.
- [7]Nie X,Leyland A,Matthews A.Deposition of layered bioceramic hydroxyapatite/Ti O2,coatings on titanium alloys using a hybrid technique of micro-arc oxidation and electrophoresis[J].Surface&Coatings Technology,2000,125(1/3):407-414.
- [8]Kim H,Miyaji F,Kokubo T,Preparation of bioactive Ti and its alloys via simple chemical surface treatment[J].Journal of Biomedical Materials Research,1996,32:407-409.
- [9]Hayakawa S,Masuda Y,Okamoto K.Liquid phase deposited titania coating to enable in vitro apatite formation on Ti6Al4V alloy[J].Journal of Mcterials Science:Materials Method,2014,25:375-381.
- [10]文九巴,雷少帆,刘亚,等.挤压态Mg-2Zn-0.4Zr-0.6Ce生物镁合金组织与性能[J].材料热处理学报.2017,38(6):67-73.WEN Jiu-ba,LEI Shao-fan,LIU Ya,et al.Microstructure and properties of extruded Mg-2Zn-0.4Zr-0.6Ce biomedical magnesium alloy[J].Transactions of Materials and Heat Treatment,2017,38(6):67-73.
- [11]雷少帆,文九巴,姚怀,等.Ce含量对Mg-2Zn-0.4Zr-x Ce生物镁合金组织及耐蚀性的影响[J].材料热处理学报,2016,37(10):96-101.LEI Shao-fan,WEN Jiu-ba,YAO Huai,et al.Effects of Ce on microstructure and properties of Mg-2Zn-0.4Zr-x Ce biomedical magnesium alloys[J].Transations of Materials and Heat Treatment,2016,37(10):96-101.
- [12]Liu Y X,Tsuru K,Hayakawa S,et al.Topotaxial nucleation and growth of Ti O2submicron-scale rod arrays on titanium substrates via sodium tetraborate glass coating[J].Journal of the Ceramic Society of Japan,2004,112(10):567-571.
- [13]Le G L,Soueidan A,Layrolle P,et al.Surface treatments of titanium dental implants for rapid osseointegration[J].Dental Materials,2007,23(7):844-854.
- [14]Albrektsson T,Wennerberg A.The impact of oral implants-past and future[J].J Can Dent Assoc,2005,71(327):1966-2042.
- [15]Hiroaki Takadama,Hyun-Min Kim,Tadashi Kokubo,et al.An X-ray photoelectron spectroscopy study of the process of apatite formation on bioactive titanium metal[J].Journal of Biomedical Materials Research,2001,55(2):185-193.
- [16]崔忠圻,覃耀春.金属学与热处理[M].北京:机械工业出版社,2014.
- [17]Hyde B G,Andersson S.Inorganic crystal structures[J].John Wiley&Sons,1989,373(53):656-657.
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