轧制及热处理对医用Mg-2Zn-0.5Nd-0.5Zr合金板材力学性能和耐蚀性能的影响Effect of rolling and heat treatment on mechanical properties and corrosion resistance of biomedical Mg-2Zn-0.5Nd-0.5Zr alloy sheet
刘天翼,谭丽丽,赵红阳,杨柯
摘要(Abstract):
用挤压轧制方法制备了厚度为1 mm的Mg-2Zn-0.5Nd-0.5Zr合金板材,并对板材进行后续退火和时效热处理,利用光学显微镜、扫描电镜、拉伸、电化学以及浸泡试验等研究了不同轧制温度和热处理对板材力学性能和耐蚀性能的影响。结果表明:轧制温度从280℃升高到330℃,合金中的Nd元素析出量减少,第二相形貌改变,板材塑性和耐蚀性提高,伸长率由9.1%提高到15.2%,腐蚀速率由0.48 mm/y降低到0.28 mm/y。退火后板材伸长率和耐蚀性均进一步提高,其中330℃+T2处理的合金板材的综合性能最好,其抗拉强度和屈服强度分别为235 MPa和158 MPa,伸长率为24.3%,腐蚀速率为0.12 mm/y。时效处理后,合金的晶界处有大量的析出相析出,第二相强化效果显著,330℃+T6组的抗拉强度和屈服强度最高,分别为275.8 MPa和255.5 MPa,但板材伸长率仅为7.6%,腐蚀速率升高到0.43 mm/y。
关键词(KeyWords): 医用镁合金;轧制;热处理;力学性能;腐蚀性能
基金项目(Foundation): 国家自然科学基金(51971222,51801220)
作者(Author): 刘天翼,谭丽丽,赵红阳,杨柯
DOI: 10.13289/j.issn.1009-6264.2021-0228
参考文献(References):
- [1] 周淑千.生物医用材料发展现状与趋势展望[J].新材料产业,2019(7):43-47.ZHOU Shu-qian.Development status and trend of biomedical materials[J].Advanced Materials Industry,2019(7):43-47.
- [2] Staiger M P,Pietak A M,Huadmai J,et al.Magnesium and its alloys as orthopedic biomaterials:A review[J].Biomaterials,2006,27 (9):1728-1734.
- [3] Tan L L,Yu X M,Wan P.Biodegradable materials for bone repairs:A review[J].Journal of Materials Science and Technology,2013,29(6):503-513.
- [4] 章晓波,薛亚军,王章忠,等.热处理对NZ30K生物镁合金力学和腐蚀性能的影响[J].材料热处理学报,2013,34(8):20-25.ZHANG Xiao-bo,XUE Ya-jun,WANG Zhang-zhong,et al.Effect of heat treatment on mechanical and corrosion properties of NZ30K bio-magnesium alloy[J] Transactions of Materials and Heat Treatment,2013,34(8):20-25.
- [5] Etim I P,Zhang W,Tan L L,et al.Influence of stamping on the biodegradation behavior of Mg-2Zn-0.5Nd (ZN20) sheet[J].Bioactive Materials,2020,5(1):133-141.
- [6] Ding Y F,Wen C E,Hodgson P,et al.Effects of alloying elements on the corrosion behavior and biocompatibility of biodegradable magnesium alloys:A review[J].Journal of Materials Chemistry B,2014,2(14):1912-1933.
- [7] Chen J X,Tan L L,Etim I P,et al.Comparative study of the effect of Nd and Y content on the mechanical and biodegradable properties of Mg-Zn-Zr-(x)Nd/Y (x=0.5,1,2) alloys[J].Materials Technology,2018,33(10):659-671.
- [8] 袁广银,章晓波,牛佳林,等.新型可降解生物医用镁合金JDBM的研究进展[J].中国有色金属学报,2011,21(10):2476-2488.YUAN Guang-yin,ZHANG Xiao-bo,NIU Jia-lin,et al Research progress of new type of degradable biomedical magnesium alloys JDBM[J].The Chinese Journal of Nonferrous Metals,2011,21(10):2476-2488.
- [9] 李军雷,谭丽丽,杨柯.挤压态Mg-Zn-Nd医用镁合金的组织与性能研究[J].中国医疗设备,2015,30(9):6-11.LI Jun-lei,TAN Li-li,YANG Ke.Investigation on micro-structures and properties of extruded Mg-Zn-Nd bio-medical magnesium alloys[J].China Medical Devices,2015,30(9):6-11.
- [10] Nene S S,Prabhu N,Kashyap B P.Microstructure refinement and its effect on specific strength and bio-corrosion resistance in ultralight Mg-4Li-lCa (LC41) alloy by hot rolling[J].Journal of Alloys and Compounds,2014,615:501-506
- [11] Liu Z D,Feyerabend F,Bohlen J,et al.Mechanical properties and degradation behavior of binary magnesium-silver alloy sheets[J].Journal of Physics and Chemistry of Solids,2019,133:142-150.
- [12] Liu H Q,Mi Z L,Tang D,et al.Effects of annealing technique on the microstructure and mechanical properties of AZ31B magnesium alloy sheets[J].Advanced Materials Research,2012,1584(2):1601-1607.
- [13] 刘光明,杨丽峡,黄庆学,等.轧后热处理工艺对AZ31镁合金铸轧板组织性能的影响[J].材料热处理学报,2019,40(6):26-32.LIU Guang-ming,YANG Li-xia,HUANG Qing-xue,et al.Effect of post-rolling heat treatment on microstructure and properties ofAZ31 magnesium alloy cast-rolled sheet[J].Transactions of Materials and Heat Treatment,2019,40(6):26-32.
- [14] Yu J M,Zhang Z M,Zhang X,et al.Study on microstructure evolution of deformed Mg-Gd-Y-Nd-Zr heat-resistant magnesium alloys after solid solution and ageing[J].Science of Sintering,2016,48(1):109-117.
- [15] 张金玲,刘阳力,周京,等.T6处理对Mg-9Al-Zn-0.16La合金耐蚀性能的影响[J].材料热处理学报,2014,35(5):64-68.ZHANG Jin-ling,LIU Yang-li,ZHOU Jing,et al.Influence of T6 treatment on corrosion resistance of Mg-9Al-Zn-0.16La alloy[J] Transactions of Materials and Heat Treatment,2014,35 (5):64-68.
- [16] Wang J F,Li Y,Huang S,et al.Study of the corrosion behavior and the corrosion films formed on the surfaces of Mg-xSn alloys in 3.5wt.% NaCl solution[J].Applied Surface Science,2014,317:1143-1150.
- [17] Kang W,Li F,Shi W Y,et al.Effect of different microstructure on corrosion behavior of magnesium alloy sheets[J].International Journal of Electrochemical Science,2020,15:9796-9810.
- [18] Birbilis N,Ralston K D,Virtanen S,et al.Grain character influences on corrosion of ecaped pure magnesium[J].Corrosion Engineering,Science and Technology,2010,45(3):224-230.
- [19] Argade G R,Panigrahi S K,Mishra R S.Effects of grain size on the corrosion resistance of wrought magnesium alloys containing neodymium[J].Corrosion Science,2012,58:145-151.
- [20] Song Y W,Han H E,Shan D Y,et al.The role of second phases in the corrosion behavior of Mg-5Zn alloy[J].Corrosion Science,2012,60:238-245.
- [21] 师慧娜,贺俊光,文九巴,等.稀土元素Dy对Mg-2Zn-0.5Zr生物镁合金组织与性能的影响[J].材料热处理学报,2020,41(1):12-18.SHI Hui-na,HE Jun-guang,WEN Jiu-ba,et al.Effect of rare earth element Dy on microstructure and properties of Mg-2Zn-0.5Zr bio-magnesium alloy[J].Transactions of Materials and Heat Treatment,2020,41(1):12-18.
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