(FeCrCoNiV)100-x-Mox(x=2,4,6,8)高熵合金的组织与力学性能Microstructure and mechanical properties of (FeCrCoNiV)100-x-Mox(x= 2, 4, 6, 8) high-entropy alloys
付朝政,毛一点,何焱,刘茵莱,王书亮
摘要(Abstract):
在各元素成相作用和降低成本的基础上,利用机械球磨与放电等离子烧结的方法首先制备了非等原子比Fe_(38)Cr_(15)Co_7Ni_(30)V_(10)高熵合金,随后添加Mo元素制备了(Fe_(38)Cr_(15)Co_7Ni_(30)V_(10))_(100-x)Mo_x(x=2、4、6、8 at%)高熵合金,研究了Mo元素添加对Fe_(38)Cr_(15)Co_7Ni_(30)V_(10)高熵合金组织与力学性能的影响。结果表明:Fe_(38)Cr_(15)Co_7Ni_(30)V_(10)高熵合金由单相FCC固溶体组成,在FCC基体相中存在部分富V的FCC相,显微硬度为(184.8±24.3) HV0.3,屈服强度为(712±5) MPa,压缩应变率大于50%;随着Mo元素的添加,(Fe_(38)Cr_(15)Co_7Ni_(30)V_(10))_(100-x)Mo_x高熵合金的相组成仍主要为FCC相,但析出了富Cr的σ相和富Mo的μ相,σ相和μ相作为硬脆相,显著提高了合金的硬度及强度,但延展性有所降低;当Mo元素为8 at%时,合金的综合性能较佳,其硬度、屈服强度、抗拉强度和应变率分别为(269.2±7.1) HV0.3、(1019±5) MPa、(1904±2) MPa和(37.0±0.6)%。
关键词(KeyWords): 高熵合金;Mo;机械球磨;放电等离子烧结;力学性能
基金项目(Foundation):
作者(Author): 付朝政,毛一点,何焱,刘茵莱,王书亮
DOI: 10.13289/j.issn.1009-6264.2025-zt11
参考文献(References):
- [1] Tsai M H,Wang C W,Tsai C W,et al.Thermal stability and performance of NbSiTaTiZr high-entropy alloy barrier for copper metallization[J].Journal of The Electrochemical Society,2011,158(11):H1161.
- [2] Yeh J W,Chen S K,Lin S J,et al.Nanostructured high-entropy alloys with multiple principal elements:Novel alloy design concepts and outcomes[J].Advanced Engineering Materials,2004,6(5):299-303.
- [3] Cantor B,Chang I T H,Knight P,et al.Microstructural development in equiatomic multicomponent alloys[J].Materials Science and Engineering A,2004,375-377:213-218.
- [4] George E P,Raabe D,Ritchie R O.High-entropy alloys[J].Nature Reviews Materials,2019,4(8):515-534.
- [5] Lu C L,Lu S Y,Yeh J W,et al.Thermal expansion and enhanced heat transfer in high-entropy alloys[J].Journal of Applied Crystallography,2013,46(3):736-739.
- [6] Kumar A,Singh A,Suhane A.A critical review on mechanically alloyed high entropy alloys:processing challenges and properties[J].Materials Research Express,2022,9(5):052001.
- [7] Wei D,Li X,Heng W,et al.Novel Co-rich high entropy alloys with superior tensile properties[J].Materials Research Letters,2019,7(2):82-88.
- [8] 周广泰.退火处理对粉末冶金制备CrFeCoNiTix高熵合金组织和性能的影响[D].哈尔滨:哈尔滨理工大学,2020.ZHOU Guang-tai.Effect of annealing treatment onmicrostructure and properties of CrFeCoNiTix high-entropyalloysprepared by powder metallurgy[D].Harbin:Harbin University of Science andTechnology,2020.
- [9] Wu S,Chia H Y,Zhang T,et al.A precipitation strengthened high entropy alloy with high (Al+Ti) content for laser powder bed fusion:Synergizing in trinsic hot cracking resistance and ultrahigh strength[J].Acta Materialia,2023,258:119193.
- [10] Wu S W,Yang T,Cao B X,et al.Multicomponent Ni-rich high-entropy alloy toughened with irregular-shaped precipitates and serrated grain boundaries[J].Scripta Materialia,2021,204:114066.
- [11] Jia Y,Wang G,Wu S,et al.A lightweight refractory complex concentrated alloy with high strength and uniform ductility[J].Applied Materials Today,2022,27:101429.
- [12] Ji W,Wang W,Wang H,et al.Alloying behavior and novel properties of CoCrFeNiMn high-entropy alloy fabricated by mechanical alloying and spark plasma sintering[J].Intermetallics,2015,56:24-27.
- [13] Wu B,Chen W,Jiang Z,et al.Influence of Ti addition on microstructure and mechanical behavior of a FCC-based Fe30Ni30Co30Mn10 alloy[J].Materials Science and Engineering A,2016,676:492-500.
- [14] 刘青.超细晶MoNbTaTiV难熔高熵合金的粉末冶金法制备及热变形行为[D].哈尔滨:哈尔滨工业大学,2021.LIU Qing.Powder metallurgy fabrication and hot deformation behaviors of ultrafine-grained MoNbTaTiV refractory high entropy alloy[D].Harbin:Harbin Institute of Technology.
- [15] Gludovatz B,Hohenwarter A,Thurston K V S,et al.Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures[J].Nature Communications,2016,7(1):10602.
- [16] Liu W H,Lu Z P,He J Y,et al.Ductile CoCrFeNiMox high entropy alloys strengthened by hard intermetallic phases[J].Acta Materialia,2016,116:332-342.
- [17] Dong Y,Lu Y,Kong J,et al.Microstructure and mechanical properties of multi-component AlCrFeNiMox high-entropy alloys[J].Journal of Alloys and Compounds,2013,573:96-101.
- [18] Shun T T,Chang L Y,Shiu M H.Microstructure and mechanical properties of multiprincipal component CoCrFeNiMox alloys[J].Materials Characterization,2012,70:63-67.
- [19] Shun T T,Chang L Y,Shiu M H.Age-hardening of the CoCrFeNiMo0.85 high-entropy alloy[J].Materials Characterization,2013,81:92-96.
- [20] Liu Y,Xie Y,Cui S,et al.Effect of Mo element on the mechanical properties and tribological responses of CoCrFeNiMox high-entropy alloys[J].Metals,2021,11(3):486.
- [21] Han C,Zhang Y,Liu J,et al.Effect of Mo content on microstructure and mechanical properties of CoCrFeNi series high-entropy alloys[J].Journal of Materials Research and Technology,2024,30:8209-8217.
- [22] Zin V,Montagner F,Miorin E,et al.Effect of Mo content on the microstructure and mechanical properties of CoCrFeNiMox HEA coatings deposited by high power impulse magnetron sputtering[J].Surface and Coatings Technology,2024,476:130244.
- [23] Miao J,Guo T,Ren J,et al.Optimization of mechanical and tribological properties of FCC CrCoNi multi-principal element alloy with Mo addition[J].Vacuum,2018,149:324-330.
- [24] Salishchev G A,Tikhonovsky M A,Shaysultanov D G,et al.Effect of Mn and V on structure and mechanical properties of high-entropy alloys based on CoCrFeNi system[J].Journal of Alloys and Compounds,2014,591:11-21.
- [25] Hasan M N,Gu J,Jiang S,et al.Effects of elemental segregation on microstructural evolution and local mechanical properties in a dynamically deformed CrMnFeCoNi high entropy alloy[J].Scripta Materialia,2021,190:80-85.
- [26] Hu Q,Ye C P,Zhang S C,et al.Mo content-depended competition between Cr2O3 enrichment and selective dissolution of CoCrFeNiMox high entropy alloys[J].npj Materials Degradation,2022,6(1):97.
- [27] Cao C M,Tong W,Bukhari S H,et al.Dynamic tensile deformation and microstructural evolution of AlxCrMnFeCoNi high-entropy alloys[J].Materials Science and Engineering A,2019,759:648-654.
- [28] Rivera-Díaz-Del-Castillo P E J,Fu H.Strengthening mechanisms in high-entropy alloys:Perspectives for alloy design[J].Journal of Materials Research,2018,33(19):2970-2982.
- [29] Jiang H,Zhang H,Huang T,et al.Microstructures and mechanical properties of Co2MoxNi2VWx eutectic high entropy alloys[J].Materials & Design,2016,109:539-546.
- [30] Yen C C,Lin S Y,Ting C L,et al.Passivation mechanisms of CoCrFeNiMox (x= 0,0.1,0.2,0.3) high entropy alloys and MP35N in 3.5 wt% NaCl aerated aqueous solutions[J].Corrosion Science,2024,228:111812.
- [31] Gao X,Liu T,Zhang X,et al.Precipitation phase and twins strengthening behaviors of as-cast non-equiatomic CoCrFeNiMo high entropy alloys[J].Journal of Alloys and Compounds,2022,918:165584.
- [32] Niu Z,Wang Y,Geng C,et al.Microstructural evolution,mechanical and corrosion behaviors of as-annealed CoCrFeNiMox (x= 0,0.2,0.5,0.8,1) high entropy alloys[J].Journal of Alloys and Compounds,2020,820:153273.
- [33] Qin G,Chen R,Zheng H,et al.Strengthening FCC-CoCrFeMnNi high entropy alloys by Mo addition[J].Journal of Materials Science & Technology,2019,35(4):578-583.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||