冉红涛,涂姝臣,李冲,张以河

• 1:北京林业大学理学院
• 2:中国地质大学(北京)材料科学与工程学院

摘要(Abstract)：

以大量堆存的固体废弃物赤泥和粉煤灰为主要原料,通过首先低温发泡成型而后高温煅烧的工艺制备了赤泥粉煤灰添加量达90 mass%以上、可用于废水除油滤料的泡沫陶瓷。研究了煅烧温度和原料配比对泡沫陶瓷性能的影响。当烧结温度为1150℃,赤泥和粉煤灰的比例为1∶1时,制备的泡沫陶瓷的显气孔率为60%以上,抗压强度在2 MPa以上。为了提高泡沫陶瓷的除油效果,泡沫陶瓷用KH-550进行表面氨基改性,改性泡沫陶瓷60 min内除油效率约为80%。改性泡沫陶瓷的除油效果和商业陶瓷滤料相当。

关键词(KeyWords)： 赤泥;粉煤灰;泡沫陶瓷;除油过滤器

Abstract:

Keywords:

基金项目(Foundation): 国家高技术研究发展计划(2012AA06A109);; 北京林业大学科技创新计划项目(TD2014-05)

作者(Author): 冉红涛,涂姝臣,李冲,张以河

DOI: 10.13289/j.issn.1009-6264.2016.03.006

参考文献(References)：

• [1]南相莉,张廷安,刘燕,等.我国赤泥综合利用分析[J].过程工程学报,2010,10(1):264-269.NAN Xiang-li,ZHANG Yan-an,LIU Yan,et al.Analysis of comprehensive utilization of red mud in china[J].The Chinese Journal of Process Engineering,2010,10(1):264-269.
• [2]付春伟,刘立强,于平坤,等.造孔剂种类对粉煤灰多孔陶瓷性能的影响研究[J].粉煤灰综合利用,2011(2):12-15.FU Chun-wei,LIU Li-qiang,YU Ping-kun,et al.Research on the effect of pore-forming agenton properties of fly ash porous ceramics[J].Fly Ash Comprehensive Utilization,2011(2):12-15.
• [3]Li Y Z,Liu C J,Luan Z K,et al.Phosphate removal from aqueous solutions using raw and activated red mud and fly ash[J].Journal of Hazardous Materials,2006,137(1):374-383.
• [4]Amritphale S S,Anshul A,Chandra N,et al.A novel process for making radiopaque materials using bauxite—red mud[J].Journal of the European Ceramic Society,2007,27(4):1945-1951.
• [5]Belviso C,Agostinelli E,Belviso S,et al.Synthesis of magnetic zeolite at low temperature using a waste material mixture:Fly ash and red mud[J].Microporous and Mesoporous Materials,2015,202:208-216.
• [6]Yang H Z,Chen C P,Pan L J,et al.Preparation of double-layer glass-ceramic/ceramic tile from bauxite tailings and red mud[J].Journal of the European Ceramic Society,2009,29(4):1887-1894.
• [7]Chen X J,Lun A X,Qu G.Preparation and characterization of foam ceramics from red mud and fly ash using sodium silicate as foaming agent[J].Ceramics International,2013,39:1923-1929.
• [8]吴庆波,刘立强,赵东,等.用粉煤灰和赤泥为原料制备多孔陶瓷的研究[J].粉煤灰综合利用,2013(4):43-47.WU Qing-bo,LIU li-qiang,ZHAO Dong,et al.Preparation study of porous ceramics with fly ash and red mud as raw materials[J].Fly Ash Comprehensive Utilization,2013(4):43-47.
• [9]Isobe T,Kameshima Y,Nakajmia A,et al.Preparation and properties of porous alumina ceramics with undirectionally oriented pores by extrusion method using a plastic substance as a pore former[J].Journal of the European Ceramic Society,2007,27(1):61-66.
• [10]白佳海.莫来石/Si C复相多孔陶瓷的制备及性能研究[J].硅酸盐通报,2006,25(6):92-94.BAI Jia-hai.Fabrication and properties of porous mullite/Si C composite ceramics[J].Bulletin of the Chinese Ceramic Society,2006,25(6):92-94.
• [11]杨家宽,张杜杜,侯健,等.热处理条件对赤泥微晶玻璃表面晶化和体积晶化的影响[J].材料热处理学报,2004,25(6):20-24.YANG Jia-kuan,ZHANG Du-du,HOU Jian,et al.Effects of heat treatment on the surface unidirectional crystallization and volume crystallization ofglass-ceramics mostly made from red mud[J].Transactions of Materials and Heat Treatment,2004,25(6):20-24.
• [12]徐晓虹,邸永江,吴建锋,等.利用固体废弃物制备多孔陶瓷滤球的研究[J].陶瓷学报,2003(4),197-200.XU Xiao-hong,DI Yong-jiang,WU Jian-feng,et al.Study on porous ceramic filtration materials for environmental protection from solid wastes[J].Journal of Ceramics,2003(4):197-200.

文章评论(Comment)：