激光功率对Zr基复合涂层微观组织与性能的影响Effect of laser power on microstructure and property of laser cladded Zr-Cu-Ni-Al coating
胡立威,李晋锋,乐国敏,曲凤盛,戚力,刘学
摘要(Abstract):
选取Zr、Cu、Ni和Al的混合粉末为原料,在纯Ti基板上利用激光熔化沉积技术制备了Zr-Cu-Ni-Al单道熔覆涂层试样。采用X射线衍射分析仪、光学显微镜、扫描电镜、显微硬度仪等研究了激光功率对熔覆层显微组织与性能的影响。研究结果表明:熔覆涂层组织由非晶和金属间化合物组成,基体Ti对熔覆层的稀释作用是涂层发生晶化的主要原因;熔覆涂层中树枝晶尺寸随着激光功率的增加而变大,熔覆试样的硬度也随着树枝晶尺寸的增大而降低,最高可达(631±4) HV0.3,约为基体硬度的5倍,对基体具有显著强化效果。
关键词(KeyWords): 激光熔覆;微观结构演化;Zr-Cu-Ni-Al单道涂层
基金项目(Foundation): 国家自然科学基金(51601176,51401189)
作者(Author): 胡立威,李晋锋,乐国敏,曲凤盛,戚力,刘学
DOI: 10.13289/j.issn.1009-6264.2018-0284
参考文献(References):
- [1] Zhang X M,Chen W P.Review on corrosion-wear resistance performance of materials in molten aluminum and its alloys[J].Transactions of Nonferrous Metals Society of China,2015,25(6):1715-1731.
- [2] 汪卫华.非晶态物质的本质和特性[J].物理学进展,2013,33(5):177-351.WANG Wei-hua.The nature and properties of amorphous matter[J].Progress in Physics,2013,33(5):177-351.
- [3] Kim H K,Lee M,Lee K R,et al.How can a minor element added to a binary amorphous alloy simultaneously improve the plasticity and glass-forming ability?[J].Acta Materialia,2013,61(17):6597-6608.
- [4] 唐翠勇,汪明文,庄哲峰,等.激光熔覆技术制备非晶合金涂层的研究进展[J].激光杂志,2015,36(12):22-25.TANG Cui-Yong,WANG Ming-wen,ZHUANG Zhe-feng,et al.Research progress of laser cladding technology to prepare amorphous alloy coating[J].Laser Journal,2015,36(12):22-25.
- [5] Williams E,Lavery N.Laser processing of bulk metallic glass:A review[J].Journal of Materials Processing Technology,2017,247:73-91.
- [6] Wu X,Hong Y.Fe-based thick amorphous-alloy coating by laser cladding[J].Surface and Coatings Technology,2001,141(2):141-144.
- [7] 胡汉起,郑启光,李梅萍,等.碳钢表面Fe-Ni-Cr-Si-B合金熔敷层的激光处理[J].工程科学学报,1994,16(2):131-134.HU Han-qi,ZHENG Qi-guang,LI Mei-ping,et al.Laser treating of layer coated with Fe-Ni-Cr-Si-B alloy on carbon steel[J].Journal of University of Science and Technology Beijing,1994,16 (2):131-134.
- [8] Zhang H,Chong K,Zhao W,et al.Effects of pulse parameters on in-situ Ti-V carbides size and properties of Fe-based laser cladding layers[J].Surface and Coatings Technology,2018,344:163-169.
- [9] Zhang T.Ni-based fully amorphous metallic coating with high corrosion resistance[J].Philosophical Magazine Letters,2006,86(1):5-11.
- [10] Gan Y,Wang W,Guan Z,et al.Multi-layer laser solid forming of Zr65Al7.5Ni10Cu17.5 amorphous coating:Microstructure and corrosion resistance[J].Optics and Laser Technology,2015,69:17-22.
- [11] Ningshen S,Mudali U K,Krishnan R,et al.Corrosion behavior of Zr-based metallic glass coating on type 304L stainless steel by pulsed laser deposition method[J].Surface and Coatings Technology,2011,205(15):3961-3966.
- [12] Jia G Z,Wang W X,Liu X,et al.Fabrication of Zr55Al10Ni5Cu30 amorphous composite coating on plain carbon steel by laser cladding and remelting[J].Materials Science Forum,2013,745/746:746-753.
- [13] Huang K J,Liu H G,Zhou C R.Laser cladding of Zr55Al10Ni5Cu30/SiC amorphous composite coatings on AZ91D magnesium alloy for improvement of corrosion resistance[J].Advanced Materials Research,2010,179/180(8/9):757-761.
- [14] 李刚,夏延秋,王彦芳,等.激光熔覆Zr-Al-Ni-Cu复合涂层组织及其摩擦磨损性能[J].摩擦学学报,2002,22(5):343-346.LI Gang,XIA Yan-qiu,WANG Yan-fang,et al.Microstructure and tribological properties of laser clad Zr-Al-Ni-Cu composite coating[J].Tribology,2002,22(5):343-346.
- [15] Lu Y,Li H,Zhang H,et al.Zr-based metallic glass coating for corrosion resistance improvement of 45 steel[J].Materials Transactions,2017,58(9):1319-1321.
- [16] Tsai P,Flores K M.A combinatorial strategy for metallic glass design via laser deposition[J].Intermetallics,2014,55(8):162-166.
- [17] Shankar A R,Mudali U K.Electrochemical and surface studies on zircaloy-4 exposed to concentrated nitric acid medium[J].Transactions of the Indian Institute of Metals,2009,62(6):54-549.
- [18] 贾高智.激光熔覆制备Zr55Al10Ni5Cu30非晶复合涂层的研究[D].太原:太原理工大学,2013.JIA Gao-zhi.Study on the fabrication of Zr55Al10Ni5Cu30 amorphous composite coating by laser cladding[D].Taiyuan:Taiyuan University of Technology,2013.
- [19] Chang Z,Wang W,Ge Y.Preparing Zr65Al7.5Ni10Cu17.5 bulk metallic glasses based on point-line-face-body theory[J].Applied Optics,2016,55(14):3787-3793.
- [20] 唐德明.纯钛表面激光熔覆锆基非晶复合涂层及其性能研究[D].湘潭:湘潭大学,2014.TANG De-ming.Synthesis and characterization of Zr-based amorphous and crystalline composite coating on Ti substrate by laser cladding[D].Xiangtan:Xiangtan University,2014.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||