王浩楠,李争显

• 1:西北有色金属研究院腐蚀与防护研究所
• 2:陕西省稀有金属表面技术工程研究中心

摘要(Abstract)：

分别采用辉光等离子冶金技术以及PVD沉积Pd膜层结合热扩散法在钛表面制备出了Ti-Pd合金层,用XRD、SEM和EDS研究合金层的相组成、微观组织和元素分布。并对Ti-Pd合金层的耐蚀性进行了研究。结果表明,两种方法制备的Ti-Pd合金层均可极大地提高钛基体在室温静态环境下耐强还原酸腐蚀的性能,其耐蚀性比纯钛提升了两个数量级。

关键词(KeyWords)： 辉光等离子;Ti-Pd合金层;耐蚀性能;钛表面

Abstract:

Keywords:

基金项目(Foundation): 国家重点基础研究发展计划项目(2012CB625100);; 陕西省科技厅“海洋先进金属材料创新团队”(2016KCT-27)

作者(Author): 王浩楠,李争显

DOI: 10.13289/j.issn.1009-6264.2016.s1.026

参考文献(References)：

• [1]莫畏.钛[M].北京:机械工业出版社,2008:885.
• [2]辛湘杰,薛峻峰,董敏.钛的腐蚀、防护与工程应用[M].合肥:安徽科学技术出版社,1988.
• [3]朱玉斌,李中奎,周廉.稀有金属材料的耐蚀性及其在化工领域的应用[J].稀有金属快报,2004,23(1):25-29.ZHU Yu-bin,LI Zhong-kui,ZHOU Lian.Corrosion resistance of rare metal materials and its application in chemical engineering[J].Rare Metals Letters,2004,23(1):25-29.
• [4]杨东,郭金明.钛合金的腐蚀机理及耐蚀钛合金的发展现状[J].钛工业进展,2011,28(2):4-7.YANG Dong,GUO Jiin-ming.Corroson mechanism of titanium alloys and development of corrosion-resistance titanium alloys[J].Titanium Industry Progress,2011,28(2):4-7.
• [5]张国英,张辉,刘艳侠,等.Pd对Ti合金钝化影响的电子理论研究[J].物理学报,2008,57(4):2404-2408.ZHANG Guo-ying,ZHANG Hui,LIU Yan-xia,et al.The electronic theory study of the influence of Pd on the passivation of Ti alloys[J].Acta Physica Sinica,2008,57(4):2404-2408.
• [6]刘贵立.钛的腐蚀与钝化机理电子理论研究[J].物理学报,2008,57(7):4441-4445.LIU Gui-li.Electronic theoretical study on the corrosion and passivation mechanism of Ti metal[J].Acta Physica Sinica,2008,57(7):4441-4445.
• [7]福塚敏夫.李佐臣,译.钯在Ti-Pd合金吸氢中的作用[J].稀有金属材料与工程,1982(4):75-81.Toshio F,LI Zuo-chen.Role of palcadium in hydrogen absorption of Ti-Pd alloy[J].Rare Metal Materials and Engineering,1982(4):75-81.
• [8]吴清枝,李佐臣,刘洪义.Ti-Pd合金耐蚀性能研究[J].稀有金属材料与工程,1982(8):29-35.WU Qing-zhi,LI Zuo-chen,LIU Hong-yi.Study on corrosion resistance of Ti-Pd alloy[J].Rare Metal Materials and Engineering,1982(8):29-35.
• [9]Gil F J,Picas J A,Manero J M,et al.Effect of the addition of palladium on grain growth kinetics of pure titanium[J].Journal of Alloys and Compounds.1997,260(1):147-152.
• [10]Brossia C S,Cragnolino G A..Effect of palladium on the corrosion behavior of titanium[J].Corrosion Science,2004,46(7):1693-1711.
• [11]陈元儒.钛表面反应离子束镀钯膜的耐腐蚀性[J].贵金属,1991,12(3):26-31.CHEN Yuan-ru.Study on the properties of corroson resistance of palladium film on titanium substrate formed by reactive ion beam plating[J].Precious Matals,1991,12(3):26-31.
• [12]Fukuzuka T,Shimogori K,Satoh H,et al.The relationship between the corrosion resistance and the surface film structure of noble metal oxide coated titanium[J].Corrosion Engineering,1979,28(8):429-436.
• [13]陈凤云,潘会波,吴玉英.防止钛缝隙腐蚀的Pd O/Ti O2涂层[J].稀有金属材料与工程,1990(5):54-58.CHEN Feng-yun,PAN Hui-bo,WU Yu-ying.Pd O/Ti O2coating for preventing crevice corrosion of titanium[J].Rare Metal Materials and Engineering,1990(5):54-58.
• [14]Kazuhiro T.Corrosion-resistant titanium alloy Ti-Ru-Ni[J].Titanium&Zirconium,1988,36(1):29-32.
• [15]Barson S D,Skeldon P.Corrosion protection of titanium by pulsed plasma deposition of palladium[J].Corrosion Science,2000,42(7):1213-1234.
• [16]Werner Z,Piekoszewski J..Alloying of Pd into Ti by pulsed plasma beams[J].Nuclear Instruments and Methods in Physics Research B,2001,175/177:767-771.
• [17]Okamoto H.Pd-Ti(Palladium-Titanium)[J].Journal of Phase Equilibria&Diffusion,2013,34(1):74-75.

文章评论(Comment)：