含Cu的HSLA钢中富Cu团簇的粗化行为及其对力学性能的影响Coarsening behavior of Cu-rich clusters in a Cu bearing HSLA steel and its effect on mechanical properties
杜瑜宾,胡小锋,宋元元,姜海昌,戎利建
摘要(Abstract):
利用原子探针层析技术(APT)对含1.4 mass%Cu的低合金高强度钢(High strength low alloy, HSLA)在450℃回火2~100 h后的富Cu团簇进行了表征,并对富Cu团簇的粗化行为及其强化行为进行了定量分析,通过拉伸实验测定了实验钢的力学性能。APT结果表明:随着回火时间的延长,富Cu团簇的等效半径逐渐增加、数量密度逐渐降低。富Cu团簇的粗化系数k,由回火2~10 h的1.9 nm~3/h,减小为50~100 h时的0.27 nm~3/h,导致富Cu团簇粗化速率下降。回火过程中,析出的富Cu团簇通过与位错的交互作用,显著提高了1.4Cu钢的屈服强度,回火2~10 h时后实验钢出现了一个屈服强度约为1076 MPa和伸长率约为19%的平台,表明实验钢具有良好的强塑性匹配。
关键词(KeyWords): HSLA钢;回火时间;富Cu团簇;粗化行为;强塑性
基金项目(Foundation): 国家重点研发计划(2016YFB0300601);; 辽宁省“兴辽英才计划”项目(LYC1907143);; 中国科学院战略重点研究项目(XDC04000000);; 辽宁省自然科学基金(2020-MS-008)
作者(Author): 杜瑜宾,胡小锋,宋元元,姜海昌,戎利建
DOI: 10.13289/j.issn.1009-6264.2021-0159
参考文献(References):
- [1] Jiao Z B,Luan J H,Zhang Z W,et al.Synergistic effects of Cu and Ni on nanoscale precipitation and mechanical properties of high-strength steels [J].Acta Materialia,2013,61(16):5996-6005.
- [2] Jain D,Isheim D,Hunter A H,et al.Multicomponent high-strength low-alloy steel precipitation-strengthened by sub-nanometric Cu precipitates and M2C carbides [J].Metallurgical and Materials Transactions A,2016,47(8):3860-3872.
- [3] Ghosh A,Mishra B,Das S,et al.Structure and properties of a low carbon Cu bearing high strength steel [J].Materials Science and Engineering A,2005,396(1/2):320-332.
- [4] Jiao Z B,Luan J H,Miller M K,et al.Precipitation mechanism and mechanical properties of an ultra-high strength steel hardened by nanoscale NiAl and Cu particles [J].Acta Materialia,2015,97(16):58-67.
- [5] 张正延,柴锋,罗小兵,等.调质态含Cu高强钢的强化机理及钢中Cu的析出行为 [J].金属学报,2019,55(6):783-791.ZHANG Zheng-yan,CHAI Feng,LUO Xiao-bing,et al.The strengthening mechanism of Cu bearing high strength steel as-quenched and tempered and Cu precipitation behavior in steel [J].Acta Metallurgica Sinica,2019,55(6):783-791.
- [6] Zou Y,Xu Y B,Han D T,et al.Aging characteristics and strengthening behavior of a low-carbon medium-Mn Cu-bearing steel [J].Materials Science and Engineering A,2018,729(21):423-432.
- [7] Kolli R P,Seidman D N.The temporal evolution of the decomposition of a concentrated multicomponent Fe-Cu-based steel [J].Acta Materialia,2008,56(9):2073-2088.
- [8] Kapoor M,Isheim D,Ghosh G,et al.Aging characteristics and mechanical properties of 1600 MPa body-centered cubic Cu and B2-NiAl precipitation-strengthened ferritic steel [J].Acta Materialia,2014,73(12):56-74.
- [9] Wen Y R,Hirata A,Zhang Z W,et al.Microstructure characterization of Cu-rich nanoprecipitates in a Fe-2.5 Cu-1.5 Mn-4.0 Ni-1.0 Al multicomponent ferritic alloy [J].Acta Materialia,2013,61(6):2133-2147.
- [10] Wen Y R,Li Y P,Hirata A,et al.Synergistic alloying effect on microstructural evolution and mechanical properties of Cu precipitation-strengthened ferritic alloys [J].Acta Materialia,2013,61(20):7726-7740.
- [11] 杜瑜宾,胡小锋,张守清,等.含1.4 wt.% Cu的HSLA钢组织和力学性能 [J].金属学报,2020,56(10):1343-1354.DU Yu-bin,HU Xiao-feng,ZHANG Shou-qing,et al.Microstructure and mechanical properties of HSLA steel containing 1.4% Cu [J].Acta Metallurgica Sinica,2020,56(10):1343-1354.
- [12] 欧平,孙坚,崔正强,等.Super304H奥氏体耐热钢时效后的组织结构 [J].材料热处理学报,2014,35(5):85-91.OU Ping,SUN Jian,CUI Zheng-qiang,et al.Microstructure of super304H austenitic heat-resistant steel after long-term aging [J].Transactions of Materials and Heat Treatment,2014,35(5):85-91.
- [13] Zhang Z W,Liu C T,Miller M K,et al.A nanoscale co-precipitation approach for property enhancement of Fe-base alloys [J].Scientific Reports,2013,3:1327.
- [14] Mukerjeed M,Dhua S K,and Sarma D S,et al.Influence of tempering on the microstructure and mechanical properties of HSLA-100 steel plates [J].Metallurgical and Materials Transactions A,2001,32(9):2259-2270.
- [15] 宋元元,赵明久,戎利建.Fe-Ni基合金时效过程中γ′相析出的原子探针层析技术研究 [J].金属学报,2018,54(9):1236-1244.SONG Yuan-yuan,ZHAO Ming-jiu,RONG Li-jian.Study on the precipitation of γ′ in a Fe-Ni base alloy during ageing by APT [J].Acta Metallurgica Sinica,2018,54(9):1236-1244.
- [16] Kelly T F,Miller M K.Invited review article:atom probe tomography [J].Review of Scientific Instruments,2007,78(3):031101.
- [17] Inoue A T A.Classification of bulk metallic glasses by atomic size difference,heat of mixing and period of constituent elements and its application to characterization of the main alloying element [J].Materials Transactions,2005,46(12):2817-2829.
- [18] Umantesv A,Olson G B.Ostwald ripening in multicomponent alloys [J].Scripta Metallurgica,1993,29(8):1135-1140.
- [19] 迟成宇,于鸿垚,董建新,等.富铜纳米析出相在18Cr9Ni3CuNbN奥氏体耐热钢中的时效强化 [J].材料热处理学报,2011,32(4):58-63.CHI Cheng-yu,YU Hong-yao,DONG Jian-xin,et al.Precipitation strengthening of Cu-rich nano-phase in 18Cr9Ni3CuNbN heat-resistant steel [J].Transactions of Materials and Heat Treatment,2011,32(4):58-63.
- [20] Salje G,Felle-Kniepmeier M.The diffusion and solubility of copper in iron [J].Journal of Applied Physics,1977,48(5):1833-1839.
- [21] Isheim D,Gagliano M S,Fine M E,et al.Interfacial segregation at Cu-rich precipitates in a high-strength low-carbon steel studied on a sub-nanometer scale [J].Acta Materialia,2006,54(3):841-849.
- [22] Russell K C,Browns L M.A dispersion strengthening model based on differing elastic moduli applied to the iron-copper system [J].Acta Metallurgica,1972,20(7):969-974.
- [23] Li Z T,Chai F,Li Y,et al.Mechanical properties and nanoparticles precipitation behavior of multi-component ultra high strength steel [J].Materials and Design,2020,191(6):108637.
- [24] Sun J,Wei S T,Lu S P.Influence of Vanadium content on the precipitation evolution and mechanical properties of high-strength Fe-Cr-Ni-Mo weld metal [J].Materials Science and Engineering A,2020,772(4):138739.
- [25] Jiao Z B,Luan J H,Miller M K,et al.Effects of Mn partitioning on nanoscale precipitation and mechanical properties of ferritic steels strengthened by NiAl nanoparticles [J].Acta Materialia,2015,84(3):283-291.
- [26] Xu S S,Zhao Y,Chen D,et al.Nanoscale precipitation and its influence on strengthening mechanisms in an ultra-high strength low-carbon steel [J].International Journal of Plasticity,2019,113(2):99-110.
- [27] Jiang S H,Wang H,Wu Y,et al.Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation [J].Nature,2017,544(7651):460-464.
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