冷加工和热处理对添加硼铈的弥散强化铜性能的影响Effect of cold working and heat treatment on properties of dispersion strengthened copper with addition of B and Ce
屠晓倩,付亚波,龚超杰,桑逸婷,陈渝,崔静
摘要(Abstract):
添加稀土铈和硼,采用溶胶凝胶和粉末烧结制备了新型氧化铝弥散强化铜。通过维氏硬度仪、扫描电镜和光学显微镜研究了冷加工率和热处理对其性能的影响。结果表明:在Cu+Al_2O_3基体中加入修饰剂硼和铈后,合金的晶格发生畸变,晶粒尺寸变小,是弥散强化铜硬度提高的主要原因。加入稀土元素铈对提高弥散强化铜的硬度比添加硼更显著。在箱式加热炉中研究了400、600、700℃加热时对其致密度的影响,发现在600℃时添加微量铈和硼,是组织细化和提高致密度的最佳温度,而加入稀土元素铈则效果更佳。
关键词(KeyWords): 弥散强化铜;退火温度;冷加工率;稀土铈
基金项目(Foundation): 全国大学生创新项目(201610350016);; 浙江省公益项目(2015C31143)
作者(Author): 屠晓倩,付亚波,龚超杰,桑逸婷,陈渝,崔静
DOI: 10.13289/j.issn.1009-6264.2017-0099
参考文献(References):
- [1]Song K X,Ping L,Bao H T.Stabilization of nano-Al2O3p/Cu composite after hightemperature an-nealing treatment[J].Materials Science Forum,2005,475-479:993-996.
- [2]钟卫佳,马可定,吴维治,等.铜加工技术实用手册[M].北京:冶金工业出版社,2007:114-115.ZHONG Wei-jia,MA Ke-ding,WU Wei-zhi,et al.Practical Handbook of Copper Processing Technology[M].Beijing:Metallurgical Industry Press,2007:114-115.
- [3]Song K X,Xing J D,Dong Q M.Optimization of the processing parameters during internal oxidation of Cu-Al alloy powders using an artificial neural network[J].Materials and Design,2005,26:337-341.
- [4]韩胜利,田宝红,刘平.点焊电极用弥散强化铜基复合材料的进展[J].河南科技大学学版,2003,24(4):16-19.HAN Sheng-li,TIAN Bao-hong,LIU Ping.Progress in the development of dispersion strengthened copper matrix composites for spot welding electrode[J].Journal of Henan University of Science and Technology,2003,24(4):16-19.
- [5]王武孝,袁森,宋文峰.Al2O3/Cu复合材料的研究进展[J].特种铸造及有色金属,1998(5):50-51.WANG Wu-xiao,YUAN Sen,SONG Wen-feng.Progress in research on Al2O3/Cu composites[J].Special Casting&Nonferrous Metals,1998(5):50-51.
- [6]Morris M A,Morris D G.Microstructual refinementand associated strength of copper alloys obtained by mechanical alloying[J].Materials Science and Engineering A,1989,111:115-127.
- [7]郭明星,汪明朴,李周,等.机械合金化制备不同粒子弥散强化铜合金的研究[J].稀有金属,2004,28(5):926-930.GUO Ming-xing,WANG Ming-pu,LI Zhou,et al.Study on preparation of dispersion strengthened copper alloys with different particles by mechanical alloying[J].Rare Metal,2004,28(5):926-930.
- [8]贾燕民,丁秉钧.制备弥散强化铜的新工艺[J].稀有金属材料与工程,2000,29(2):141-143.JIA Yan-min,DING Bing-jun.Preparation of dispersion strengthened copper[J].Rare Metal Materials and Engineering,2000,29(2):141-143.
- [9]高闰丰,梅炳初,朱教群,等.弥散强化铜基复合材料的研究现状与展望[J].稀有金属快报,2005,24(8):1-7.GAO Run-feng,MEI Bing-chu,ZHU Jiao-qun,et al.Studies and prospects of diffusion strengthened copper matrix composites[J].Rare Metal Express,2005,24(8):1-7
- [10]Fu Y B,Wang Z J,Xu A J.Al2O3Nanoparticles induced high dezincification corrosion resistance of 71 wt%Cu-Zn alloy[J].Science of Advanced Materials,2015,7(12):2570-2575.
- [11]Fu Y B,Lu Y P,Wang Z J,et al.Microstructural refinement and performance improvement of Cu-36 wt%Zn alloy by Al2O3nanoparticles coupling electromagnetic stirring[J].Rare Metals,2016,9(67):1-6.
- [12]王同敏,邹存磊,李廷举,等.添加稀土La的原位Ti B 2增强铜基复合材料及其制备方法:中国,201510330692[P].2015-06-12.
- [13]张文毓.氧化铝弥散强化铜应用进展[J].世界有色金属,2008(7):60-61.Zh ANG Wen-yu.Application progress of alumina dispersion strengthened copper[J].World Nonferrous Metals,2008(7):60-61.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||