镀镍碳纳米管对激光熔覆钴基合金涂层组织和性能的影响Effect of nickel-coated carbon nanotubes on microstructure and properties of laser cladding cobalt-based alloy coatings
孙辉,徐进,胡树兵,秦岩平,田静静,廖攀
摘要(Abstract):
在同一工艺参数下在00Cr13Ni4Mo马氏体不锈钢表面制备镀镍碳纳米管质量分数为0.5%~2.0%的钴基合金涂层,利用扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、显微硬度计、摩擦磨损测试和空泡腐蚀测试等研究了涂层的显微组织、物相组成、显微硬度、耐磨损性能和耐空泡腐蚀性能。结果表明:激光熔覆过程使部分碳纳米管烧损,一部分得以保留,当碳纳米管含量达到1.0%时涂层出现了较明显的裂纹;随着碳纳米管含量的增加,涂层的硬度最高达到680 HV0.05;当碳纳米管含量为1.0%时,涂层的磨损量最低,为0.67 mg,耐磨性提高;由于适量纳米碳管对涂层的细晶强韧化作用,与Stellite6涂层相比,当碳纳米管含量为0.5%时,涂层的空泡腐蚀质量损失由4.93 mg降低到1.86 mg,冲蚀质量损失由1.5 mg降低至0.7 mg,表明涂层的抗空蚀性能和抗冲蚀性能均提高;碳纳米管含量超过1.0%时涂层的抗空蚀性能和抗冲蚀性能均下降。
关键词(KeyWords): 钴基合金;空泡腐蚀;激光熔覆;纳米碳管
基金项目(Foundation): 国家重点研发计划课题(2020YFB2010304)
作者(Author): 孙辉,徐进,胡树兵,秦岩平,田静静,廖攀
DOI: 10.13289/j.issn.1009-6264.2022-0649
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