朱文光,李娜,苏航,王邃,张聪惠

• 1:西安建筑科技大学冶金工程学院
• 2:中国石油集团工程材料研究院有限公司

摘要(Abstract)：

微合金高强度钢在油气运输领域的应用长达60余年,随着石油天然气工业的不断发展,对管线钢提出了高强韧、高可焊和抗氢致开裂等综合性能要求。首先回顾了微合金高强度钢的发展,探讨了Ti、Nb、V等微合金元素和Mn、Ni、Mo、Cu等合金元素对管线钢再结晶和相变的影响;在此基础上对微合金管线钢的加工工艺(控轧控冷(TMCP)、加速冷却(ACC)、超快冷(SFC)、在线加热配分(HOP)以及高温轧制(HTP))进行了详细介绍;并深入分析了控制轧制过程中奥氏体的再结晶行为及合金元素对奥氏体再结晶的影响机制,控制冷却过程中的相变行为及组织调控方法。最后,对微合金高强度钢的强韧化机理进行了分析,讨论了基于固溶强化、细晶强化、析出强化以及位错强化的强度计算方法,分析了晶粒尺寸、微观组织类型及取向相关性对冲击韧性的影响。可为新一代高强韧管线钢成分设计、加工工艺优化及组织调控提供理论与技术参考。

关键词(KeyWords)： 管线钢;HSLA钢;控轧控冷;再结晶;组织调控;强韧化

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金青年项目(52101113)

作者(Author): 朱文光,李娜,苏航,王邃,张聪惠

DOI: 10.13289/j.issn.1009-6264.2024-0468

参考文献(References)：

• [1]高振宇,张慧宇,高鹏. 2022年中国油气管道建设新进展[J].国际石油经济,2023,31(3):16-23.GAO Zhen-yu,ZHANG Hui-yu,GAO Peng. New progress in China’s oil and gas pipeline construction in 2022[J]. International Petroleum Economics,2023,31(3):16-23.
• [2]李鹤林.油气输送钢管的发展动向与展望[J].焊管,2004(6):1-11.LI He-lin. Developing pulse and prospect of oil and gas transmission pipe[J]. Welded Pipe and Tube,2004(6):1-11.
• [3]李鹤林,吉玲康,田伟.西气东输一、二线管道工程的几项重大技术进步[J].天然气工业,2010,30(4):1-9.LI He-lin,JI Ling-kang,TIAN Wei. Significant technical progress in the west-east gas pipeline projects line one and line two[J].Natural Gas Industry,2010,30(4):1-9.
• [4] Cone E F. Carbon and Low-Alloy Steels. In:Symposium on High-Strength Constructional Metals[M]. US:ASTM International,1936.
• [5] Cochrane R C. 6-Phase Transformations in Microalloyed High Strength Low Alloy(HSLA)Steels. In:Phase Transformations in Steels[M]. UK:Woodhead Publishing,2012.
• [6] Bai Q,Bai Y. 31-Use of High-Strength Pipeline Steels. In:Subsea Pipeline Design,Analysis,and Installation[M]. Boston:Gulf Professional Publishing,2014.
• [7] Vervynckt S,Verbeken K,Lopez B,et al. Modern HSLA steels and role of non-recrystallisation temperature[J]. International Materials Reviews,2012,57(4):187-207.
• [8]汤海东,王绍智,唐元生.西气东输二线东段上海支干线X70长输管线的焊接施工[J].石油化工建设,2011,33(6):57-59.TANG Hai-dong,WANG Shao-zhi,TANG Yuan-sheng. Welding construction of X70 long-distance pipeline of Shanghai branch trunk line in the east section of the second west-east gas pipeline[J]. Petroleum and Chemical Construction,2011,33(6):57-59.
• [9]张伟卫,熊庆人,吉玲康,等.国内管线钢生产应用现状及发展前景[J].焊管,2011,34(1):5-8.ZHANG Wei-wei,XIONG Qing-ren,JI Ling-kang,et al. Application and prospect of pipeline steel in China[J]. Welded Pipe and Tube,2011,34(1):5-8.
• [10]王春明,鲁强,吴杏芳.管线钢的合金设计[J].鞍钢技术,2004(6):22-28.WANG Chun-ming,LU Qiang,WU Xing-fang. Alloy design of pipeline steel[J]. Angang Technology,2004(6):22-28.
• [11] Shanmugam S,Misra R D K,Hartmann J,et al. Microstructure of high strength niobium-containing pipeline steel[J]. Materials Science and Engineering A,2006,441(1):215-229.
• [12] Nayak S S,Misra R D K,Hartmann J,et al. Microstructure and properties of low manganese and niobium containing HIC pipeline steel[J]. Materials Science and Engineering A,2008,494(1/2):456-463.
• [13] Shi X,Yan W, Wang W, et al. Novel Cu-bearing high-strength pipeline steels with excellent resistance to hydrogen-induced cracking[J]. Materials&Design,2016,92:300-305.
• [14] Ren Y,Zhang S,Wang S,et al. Experimental study on 830 MPa grade pipeline steel containing chromium[J]. International Journal of Minerals,Metallurgy and Materials,2009,16(3):273-277.
• [15] Han S Y,Shin S Y,Seo C H,et al. Effects of Mo,Cr,and V additions on tensile and charpy impact properties of API X80 pipeline steels[J]. Metallurgical and Materials Transactions,2009,40(8):1851-1862.
• [16] Bjorhovde R. Development and use of high performance steel[J]. Journal of Constructional Steel Research,2004,60(3):393-400.
• [17] Miao C L,Shang C J,Zurob H S,et al. Recrystallization,precipitation behaviors,and refinement of austenite grains in high Mn,high Nb steel[J]. Metallurgical and Materials Transactions,2012,43(2):665-676.
• [18] Su L,Li H,Lu C,et al. Transverse and z-direction CVN impact tests of X65 line pipe steels of two centerline segregation ratings[J]. Metallurgical and Materials Transactions,2016,47(8):3919-3932.
• [19] Sobral M D C,Mei P R,Kestenbach H J. Effect of carbonitride particles formed in austenite on the strength of microalloyed steels[J]. Materials Science and Engineering A,2003,367(1):317-321.
• [20] Deardo A J. Niobium in modern steels[J]. International Materials Reviews,2003,48(6):371-402.
• [21] Kejian H,Baker T N. The effects of small titanium additions on the mechanical properties and the microstructures of controlled rolled niobium-bearing HSLA plate steels[J]. Materials Science and Engineering A,1993,169(1):53-65.
• [22] Xu G,Gan X L,Ma G J,et al. The development of Ti-alloyed high strength microalloy steel[J]. Materials and Design,2009,31(6):2891-2896.
• [23] Mohrbacher H,Sun X,Yong Q L,et al. Mo Nb-Based Alloying Concepts for Low-Carbon Bainitic Steels. In:Advanced Steels[M].China:Metallurgical Industry Press,2011.
• [24] Duan L N,Chen Y,Liu Q Y,et al. Microstructures and mechanical properties of X100 pipeline steel strip[J]. Journal of Iron and Steel Research International,2014,21(2):227-232.
• [25] Yin Y Q,Lei X W,Wu K M. Current status and prospectus of ultra-high strength pipeline steel development[J]. China Metallurgy,2012,22(9):2-8.
• [26]李国鹏,韩秀林,赵波,等. X80和X90管线钢热影响区组织与韧性对比[J].焊管,2014,37(7):13-17.LI Guo-peng,HAN Xiu-lin,ZHAO Bo,et al. Comparison of microstructure and toughness of X80 and X90 pipeline heat-affected zone(HAZ)[J]. Welded Pipe and Tube,2014,37(7):13-17.
• [27]张凯,邱春林,赵宇,等.硼对高级别管线钢连续冷却转变与动态再结晶的影响[J].钢铁研究学报,2011,23(3):22-28.ZHANG Kai,QIU Chun-lin,ZHAO Yu,et al. Effects of boron on continuous cooling transformation and dynamic recrystallization of high grade pipeline steel[J]. Journal of Iron and Steel Research,2011,23(3):22-28.
• [28]柳美玲,王萍,汤亨强,等. X100级管线钢TMCP工艺研究[J].热加工工艺,2019,48(15):107-109.LIU Mei-lin, WANG Ping, TANG Heng-qiang, et al. Study on TMCP technology of X100 pipeline steel[J]. Hot Working Technology,2019,48(15):107-109.
• [29]黄少文,陈爱娇,霍孝新,等.高钢级X100管线钢的韧性和显微组织[J].金属热处理,2014,39(10):96-101.HUANG Shao-wen,CHEN Ai-jiao,HUO Xiao-xin,et al. Toughness and microstructure of high grade X100 pipeline steel[J]. Heat Treatment of Metals,2014,39(10):96-101.
• [30]胡平,章传国,郑磊.冷却工艺和成分对X100管线钢组织与性能的影响[J].金属热处理,2015,40(3):140-146.HU Ping,ZHANG Chuan-guo,ZHENG Lei. Effects of cooling process and chemical composition on microstructure and properties of X100 pipeline steel[J]. Heat Treatment of Metals,2015,40(3):140-146.
• [31] Beladi H,Kelly G L,Hodgson P D. Ultrafine grained structure formation in steels using dynamic strain induced transformation processing[J]. International Materials Reviews,2007,52(1):14-28.
• [32] Medina S F,Hernandez C A. Modelling of the dynamic recrystallization of austenite in low alloy and microalloyed steels[J]. Acta Materialia,1996,44(1):165-171.
• [33] Medina S F,Mancilla J E. Static recrystallization of austenite and strain induced precipitation kinetics in titanium microalloyed steels[J]. Acta Metallurgica et Materialia,1994,42(12):3945-3951.
• [34] Medina S F, Quispe A. Improved model for static recrystallization kinetics of hot deformed austenite in low alloy and Nb/V microalloyed steels[J]. ISIJ International,2001,41(7):774-781.
• [35]魏洁,唐广波,刘正东.碳锰钢热变形行为及动态再结晶模型[J].钢铁研究学报,2008,20(3):31-35.WEI Jie,TANG Guang-bo,LIU Zheng-dong. Hot deformation and dynamic recrystallization models of C-Mn steel[J]. Journal of Iron and Steel Research,2008,20(3):31-35.
• [36] Fernández A I,Uranga P,López B,et al. Dynamic recrystallization behavior covering a wide austenite grain size range in Nb and Nb-Ti microalloyed steels[J]. Materials Science and Engineering A,2003,361(1/2):367-376.
• [37] Zhao B,Zhao T,Li G,et al. The kinetics of dynamic recrystallization of a low carbon vanadium-nitride microalloyed steel[J].Materials Science and Engineering A,2014,604:117-121.
• [38] Shaban M,Eghbali B. Determination of critical conditions for dynamic recrystallization of a microalloyed steel[J]. Materials Science and Engineering A,2010,527(16/17):4320-4325.
• [39]陈庆军,康永林,孙浩,等. X70管线钢动态再结晶行为的模拟[C]//全国博士生学术论坛———材料科学分论坛,北京,2006:1-3.CHEN Qing-jun,KANG Yong-lin,SUN Hao,et al. Simulation on dynamic recrystallization behavior of X70 pipeline steel[C]//National Doctoral Academic Forum of Materials Science———Materials Science Sub-forum,Beijing,2006:1-3.
• [40] Baker T N. Titanium microalloyed steels[J]. Ironmaking&Steelmaking,2019,46(1):1-55.
• [41] Baker T N. Processes,microstructure and properties of vanadium microalloyed steels[J]. Materials Science and Technology,2009,25(9):1083-1107.
• [42] Mekkawy M F,El-Fawakhry K A,Mishreky M L,et al. Effect of interrupted accelerated cooling on mechanical properties and structure of vanadium and titanium microalloyed steel bars[J]. Materials Science and Technology,1991,7(1):28-36.
• [43] Akamatsu S,Hasebe M,Senuma T,et al. Thermodynamic calculation of solute carbon and nitrogen in Nb and Ti added extra-low carbon steels[J]. ISIJ International,1994,34(1):9-16.
• [44] Maruyama N,Uemori R,Sugiyama M. The role of niobium in the retardation of the early stage of austenite recovery in hot-deformed steels[J]. Materials Science and Engineering A,1998,250:2-7.
• [45] Speer J G,Hansen S S. Austenite recrystallization and carbonitride precipitation in niobium microalloyed steels[J]. Metallurgical Transactions A,1989,20(1):25-38.
• [46] Uranga P,Ana Isabel F C,López B,et al. Optimization of rolling conditions in Nb microalloyed steel processed by thin slab casting and direct rolling route:processing maps[J]. Materials Science Forum,2005,531(500/501):245-252.
• [47] Shukla R,Ghosh S K,Chakrabarti D,et al. Microstructure,texture,property relationship in thermo-mechanically processed ultra-low carbon microalloyed steel for pipeline application[J]. Materials Science and Engineering A,2013,587:201-208.
• [48] Cho S H, Kang K B, Jonas J J. Mathematical modeling of the recrystallization kinetics of Nb microalloyed steels[J]. ISIJ International,2001,41(7):766-773.
• [49] Takahashi A,Iino M. Microstructural refinement by Cu addition and its effect on strengthening and toughening of sour service line pipe steels[J]. ISIJ International,1996,36(2):241-245.
• [50] Bouet M,Root J H,Es-Sadiqi E,et al. The effect of Mo in Si-Mn Nb bearing TRIP steels[J]. Materials Science Forum,1998,284-286:319-326.
• [51] Kong J H,Zhen L,Guo B,et al. Influence of Mo content on microstructure and mechanical properties of high strength pipeline steel[J]. Materials&Design,2004,25(8):723-728.
• [52]刘干,孔祥磊,黄明浩,等.冷却速率对超高强度X90M管线钢相变行为的影响[J].金属热处理,2024,49(5):162-167.LIU Gan,KONG Xiang-lei,HUANG Ming-hao,et al. Effect of cooling rate on phase transformation behavior of ultra-high strength X90M pipeline steel[J]. Heat Treatment of Metals,2024,49(5):162-167.
• [53]齐亮,彭凯,周军,等. TMCP工艺对X100管线钢M/A岛的影响[J].材料导报,2016,30(2):95-98.QI Liang,PENG Kai,ZHOU Jun,et al. Effect of TMCP(thermo-mechanical control process on M/A islands of X100 pipeline steel[J]. Materials Review,2016,30(2):95-98.
• [54] Cheng S X,Lv R S,Cheng F,et al. Microstructure and properties of X100 large-deformability pipeline steel based on heating online partitioning[J]. Materials Today Communications,2023,35:105771.
• [55]肖宝亮,许云波,张福生,等.“高温大变形+超快冷”工艺在管线钢生产中的应用[J].钢铁,2010,45(6):49-53.XIAO Bao-liang,XU Yun-bo,ZHANG Fu-sheng,et al. Application of large deformation at high temperature and ultra-fast cooling process in production of pipeline steel[J]. Iron and Steel,2010 45(6):49-53.
• [56] Cheng S,Zhang X,Zhang J,et al. Effect of coiling temperature on microstructure and properties of X100 pipeline steel[J].Materials Science and Engineering A,2016,666:156-164.
• [57]张涛,侯华兴,刘明,等. HTP工艺超低碳贝氏体钢Q620CFD中厚板的开发[J].鞍钢技术,2010(6):27-30.ZHANG Tao,HOU Hua-xing, LIU Ming, et al. Development of UDCBS Q620CFD medium steel plate by HTP[J]. Angang Technology,2010(6):27-30.
• [58]兰亮云,邱春林,赵德文.高钢级管线钢的常规TMCP工艺与HTP工艺[J].轧钢,2009,26(5):39-42.LAN Liang-yun,QIU Chun-lin,ZHAO De-wen. Normal TMCP and HTP technologies for high grade pipeline steels[J]. Steel Rolling,2009,26(5):39-42.
• [59]刘阳,刘峻峰,张斌,等.我国长输天然气用管线钢的发展现状与趋势[J].材料热处理学报,2024,45(3):98-112.LIU Yang, LIU Jun-feng, ZHANG Bin, et al. Development status and trend of pipeline steel for long-distance natural gas transportation in China[J]. Transactions of Materials and Heat Treatment,2024,45(3):98-112.
• [60]冯路路,高秀华,邱春林. HTP型X70管线钢的开发[J].热加工工艺,2010,39(6):57-60.FENG Lu-lu, GAO Xiu-lin, QIU Chun-lin, et al. Development of X70 pipeline steel produced by HTP[J]. Hot Working Technology,2010,39(6):57-60.
• [61]侯华兴,杨颖,张哲,等. HTP技术在高强度特厚板生产中的应用[J].钢铁,2012,47(2):53-57.HOU Hua-xing,YANG Ying,ZHANG Zhe,et al. Application of HTP process in production of ultra-heavy steel with high strength[J]. Iron and Steel,2012,47(2):53-57.
• [62]缪成亮,尚成嘉,曹建平,等. HTP X80管线钢的晶粒细化与组织控制[J].钢铁,2009,44(3):62-66.MIAO Cheng-liang,SHANG Cheng-jia,CAO Jian-ping,et al. Grain refinement and microstructure control of HTP X80 pipeline steel[J]. Iron and Steel,2009,44(3):62-66.
• [63] Pickering F B. Physical Metallurgy and the Design of Steels[M]. London:Applied Science Publishers,1978.
• [64] Kamikawa N,Huang X,Tsuji N,et al. Strengthening mechanisms in nanostructured high-purity aluminium deformed to high strain and annealed[J]. Acta Materialia,2009,57:4198-4208.
• [65] Kamikawa N,Abe Y,Miyamoto G,et al. Tensile behavior of Ti,Mo-added low carbon steels with interphase precipitation[J]. ISIJ International,2014,54(1):212-221.
• [66] Kamikawa N,Sato K,Miyamoto G,et al. Stress-strain behavior of ferrite and bainite with nano-precipitation in low carbon steels[J]. Acta Materialia,2015,83:383-396.
• [67] Gladman T,Holmes G,McIvor I D. Effects of Second-Phase Particles on Strength,Toughness and Ductility. In:Effect of Second Phase Particles on Mechanical Properties of Steel[M]. London:Iron and Steel Institute,1971.
• [68] Li X C,Zhao J X,Jia S J,et al. Ultrafine microstructure design of high strength pipeline steel for low temperature service:The significant impact on toughness[J]. Materials Letters,2021,303:130429.
• [69] Zhao M C,Yang K,Shan Y Y. Comparison on strength and toughness behaviors of microalloyed pipeline steels with acicular ferrite and ultrafine ferrite[J]. Materials Letters,2003,57(9/10):1496-1500.
• [70] Li X,Zhao J, Wang J, Wang X, et al. Effect of boundaries on toughness in high-strength low-alloy steels from the view of crystallographic misorientation[J]. Materials Letters,2020,259:126841-126841.
• [71] Ghosh A,Kundu S,Chakrabarti D. Effect of crystallographic texture on the cleavage fracture mechanism and effective grain size of ferritic steel[J]. Scripta Materialia,2014,81:8-11.
• [72] Tamehiro H, Murata M, Habu R, et al. Optimum microalloying of niobium and boron in HSLA steel for thermomechanical processing[J]. ISIJ International,1987,27(2):120-129.

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