铝与氮化硼的反应机理及其复合材料的组织和性能Reaction mechanism of aluminum with boron nitride and microstructure and properties of its composites
杨思尧,李树丰,张鑫,刘磊,潘登,高丽娜,张亚锟,李波
摘要(Abstract):
采用粉末冶金法,通过六方氮化硼纳米片(BNNSs)与Al的原位反应制备多元混杂增强铝基复合材料,研究了BNNSs与Al的原位反应机理以及反应前后对复合材料的相组成、微观组织、界面结构和力学性能的影响。结果表明:BNNSs与Al混合粉末在630℃放电等离子烧结致密化后,BNNSs与Al并未发生反应。基于此,将烧结坯体在不同温度下进行了热处理,随着热处理温度的升高,B、N原子在Al基体中的扩散速率加快,使得BNNSs与Al的反应进程加剧。经过反应后,基体界面及晶界处弥散分布的AlB_2、AlN能够有效提高复合材料的综合性能。在750℃热处理后,复合材料的抗拉强度、屈服强度、伸长率和导电率分别达到166 MPa、131 MPa、20.4%和50.9%IACS;并且当Al与BNNSs反应充分时,其热导率达到173.4 W·m~(-1)·K~(-1)。
关键词(KeyWords): 粉末冶金;铝基复合材料;高温热处理;原位反应机理;综合性能
基金项目(Foundation): 国家自然科学基金(51871180)
作者(Author): 杨思尧,李树丰,张鑫,刘磊,潘登,高丽娜,张亚锟,李波
DOI: 10.13289/j.issn.1009-6264.2021-0277
参考文献(References):
- [1] 张鑫.CNTs-SiCp双纳米相增强铝基复合材料的制备及其协同强化机制[D].西安:西安理工大学,2017.ZHANG Xin.Fabrication and synergistic-strengthening mechanism of CNTs-SiCp dual-nano reinforcements in aluminum matrix composites[D].Xi’an:Xi’an University and Technology,2017.
- [2] 蒋民华.神奇的新材料[M].山东:山东科学技术出版社,2007.JIANG Min-hua.Magical New Materials[M].Shandong:Shandong Science and Technology Press,2007.
- [3] Jin P,Xiao B,Wang Q,et al.Effect of hot extrusion on interfacial microstructure and tensile properties of SiCp/2009Al composites fabricated at different hot pressing temperatures[J].Journal of Materials Science and Technology,2011,27(6):518-524.
- [4] 邱峰.铝基合金复合材料制备及性能研究[D].沈阳:东北大学,2013.QIU Feng.Research on preparation and performance of aluminum-based alloy composite[D].Shenyang:Northeastern University,2013.
- [5] 耿林,范国华.金属基复合材料的构型强韧化研究进展[J].中国材料进展,2016,35(9):686-693.GENG Lin,FAN Guo-hua.Research progress of structural strengthening and toughening of metal matrix composites[J].Materials China,2016,35(9):686-693.
- [6] Ghomashchi M R,Vikhrov A.Squeeze casting:an overview[J].Journal of Materials Processing Technology,2000,101(1):1-9.
- [7] Bakshi S R,Lahiri D,Agarwal A.Carbon nanotube reinforced metal matrix composites-a review[J].International Materials Reviews,2010,55(1):41-64.
- [8] Zhang L,Xu H Q,Wang Z,et al.Mechanical properties and corrosion behavior of Al/SiC composites[J].Journal of Alloys and Compounds,2016,678:23-30.
- [9] 翟凤瑞,单科,卢敏,等.六方氮化硼陶瓷的烧结及其结构和性能[J].硅酸盐学报,2018,46(6):807-812.ZHAI Feng-rui,SHAN Ke,LU Min,et al.Sintering,structure and properties of hexagonal boron nitride ceramics[J].Journal of the Chinese Ceramic Society,2018,46(6):807-812.
- [10] Steinman A E,Corthay S,Firestein K L,et al.Al-based composites reinforced with AlB2,AlN and BN phases:Experimental and theoretical studies[J].Materials and Design,2018,141:88-98.
- [11] Kvashnin D G,Firestein K L.Al-BN interaction in a high-strength light weight Al/BN metal-matrix composite:Theoretical modelling and experimental verification[J].Journal of Alloys and Compounds 2019,782:875-880.
- [12] Povstugar I V,Streletskii A N,Permenov D G,et al.Mechanochemical synthesis of activated Me-BN (Me:Al,Mg,Ti) nanocomposites[J].Journal of Alloys and Compounds,2009,483(1/2):298-301.
- [13] Xia Z P,Li Z Q,Lu C J,et al.Structural evolution of Al/BN mixture during mechanical alloying[J].Journal of Alloys and Compounds,2005,399(1/2):139-143.
- [14] Yum K,Yu M F.Measurement of wetting properties of individual boron nitride nanotubes with the wilhelmy method using a nanotube-based force sensor[J].Nano Letters,2015,6(2):329-333.
- [15] Shen P,Fujii H,Nogi K.Effect of temperature and surface roughness on the wettability of boron nitride by molten Al[J].Journal of Materials Science,2007,42(10):3564-3568.
- [16] Finnis M W.The theory of metal - ceramic interfaces[J].Journal of Physics Condensed Matter,1996,8(32):5811-5836.
- [17] Mills K C,Su Y C.Review of surface tension data for metallic elements and alloys:Part 1-Pure metals[J].Metallurgical Reviews,2006,51(6):329-351.
- [18] Shen P,Fujii H,Nogi K.Effect of temperature and surface roughness on the wettability of boron nitride by molten Al[J].Journal of Materials Science,2007,42(10):3564-3568.
- [19] 张强,武高辉,韩杰才.AlN颗粒增强铝基复合材料的微观组织与力学性能[C]//中国工程院化工,冶金与材料工程学部第五届学术会议,中国工程院,2005.ZHANG Qiang,WU Gao-hui,HAN Jie-cai.Microstructure and mechanical properties of AlN particle reinforced aluminum matrix composites[C]//Chinese Academy of Engineering Chemical Industry,The Fifth Academic Conference of the Department of Metallurgy and Materials Engineering,Chinese Academy of Engineering,2005.
- [20] 向常虎.AlN陶瓷的电性能研究[D].武汉:华中科技大学,2013.XIANG Chang-hu.Study of AlN ceramics’ electrical properties[D].Wuhan:Huazhong University of Science and Technology,2013.
- [21] 温斌,冯幸.金属热导率的第一性原理计算方法在铝中的应用[J].燕山大学学报,2015,39(4):298-305.WEN bin,FENG Xing.Application of first-principles calculation method of metal thermal conductivity in aluminum[J].Journal of Yanshan University,2015,39(4):298-305.
- [22] Lv H,Chen G,Ye H,et al.Synthesis of monocrystal aluminum nitride nanowires at low temperature[J].Journal of Applied Physics,2007,101(5):5279.
- [23] Yang J,Liu T W,Hsu C W,et al.Controlled growth of aluminium nitride nanorod arrays via chemical vapour deposition[J].Nanotechnology,2014,17(11):S321-S326.
- [24] Martin F,Muralt P,Dubois M A,et al.Thickness dependence of the properties of highly c-axis textured AlN thin films[J].Journal of Vacuum Science and Technology A Vacuum Surfaces and Films,2004,22(2):361-365.
- [25] Abdel-Hamid A A,Hamar-Thibault S,Hamar R.Crystal morphology of the compound TiB2[J].Journal of Crystal Growth,1985,71(3):744-750.
- [26] Eppisch C D,Liu G,Hall A,et al.The crystallization and growth of AlB2 single crystal flakes in aluminum[J].Journal of Materials Research,1998,13(12):3485-3498.
- [27] Lahiri D,Singh V,Lu H L,et al.Insight into reactions and interface between boron nitride nanotube and aluminum[J].Journal of Materials Research,2012,27(21):2760-2770.
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