WC含量对弥散铜-WC复合材料热变形行为的影响Effect of WC content on hot deformation behavior of Al2O3/Cu-WC composites
冯江,田保红,张毅,刘勇,李全安
摘要(Abstract):
采用真空热压烧结工艺成功制备WC体积分数为0、10%、20%的弥散铜-WC复合材料,分析了其显微组织和性能;并利用Gleeble-1500D热力模拟试验机,研究了该复合材料在变形温度为350~750℃,应变速率为0.01~5 s-1条件下的热变形行为。结果表明:复合材料的相对密度在95%以上,随着WC含量的增加,其导电率下降、硬度升高。弥散铜-WC复合材料高温流变应力-应变曲线主要以动态再结晶机制为特征,峰值应力随变形温度的降低或应变速率的升高而增加;高温变形条件下弥散铜-WC复合材料流变应力本构方程可以用双曲线正弦方程和Z参数描述;其热变形激活能分别为193.81,208.35和229.17 kJ/mol。
关键词(KeyWords): 弥散铜-WC复合材料;性能;热变形;本构方程
基金项目(Foundation): 国家自然科学基金资助项目(51101052);; 河南高校科技创新团队支持计划(2012IRTSTHN008)
作者(Author): 冯江,田保红,张毅,刘勇,李全安
DOI: 10.13289/j.issn.1009-6264.2014.05.002
参考文献(References):
- [1]田保红,宋克兴,刘平.高性能弥散强化铜基复合材料及其制备技术[M].北京:科学出版社,2011:57-59.
- [2]王孟君,张立勇,刘新宇,等.WC/Cu复合材料制备及其高温性能[J].材料科学与工程学报,2003,21(4):528-530.WANG Meng-jun,ZHANG Li-yong,LIU Xin-yu,et al.Preparation and high-temperature property of WC/Cu composite[J].Journal of Materials Science&Engineering,2003,21(4):528-530.
- [3]张立勇,王孟君,刘心宇,等.WC含量对弥散强化铜Cu/WC组织与性能影响的研究[J].稀有金属,2003,27(1):108-111.ZHANG Li-yong,WANG Meng-jun,LIU Xin-yu,et al.Effect of WC content on structure and property of dispersion strengthened copper of Cu/WC[J].Chinese Journal of Rare Metals,2003,27(1):108-111.
- [4]QU Hai-xia,ZHU Shi-gen,LI Qian,et al.Influence of sintering temperature and holding time on the densification,phase transformation,microstructure and properties of hot pressing WC-40vol.%Al2O3composites[J].Ceram Int,2012,38:1371-1380.
- [5]Sherif M,El-Eskandarany.Fabrication and characterizations of new nanocomposite WC/Al2O3materials by room temperature ball milling and subsequent consolidation[J].J Alloys Compd,2005,391:228-235.
- [6]陈立力,谢春生,严磊.真空热压绕结对Cu/WC复合材料性能的影响[J].热加工工艺,2009,38(2):58-60.CHEN Li-li,XIE Chun-sheng,YAN Lei.Effect of vacuum hot-pressed sinter on properties of Cu/WC composite[J].Hot Working Technology,2009,38(2):58-60.
- [7]刘彬彬,鲁岩娜,谢建新.热压烧结制备近全致密W-Cu梯度热沉材料[J].中国有色金属学报,2007,17(9):1410-1416.LIU Bin-bin,LU Yan-na,XIE Jian-xin.Fabrication of tungsten/copper functionally gradient materials with nearly full density by hot press[J].The Chinese Journal of Nonferrous Metals,2007,17(9):1410-1416.
- [8]张晓伟,田保红,张毅,等.真空热压烧结W(50)/Cu-Al2O3的热压缩变形行为[J].材料热处理学报,2011,32(8):41-46.ZHANG Xiao-wei,TIAN Bao-hong,ZHANG Yi,et al.Hot compression deformation behavior of W(50)/Cu-Al2O3composites prepared by vacuum hot-press sintering[J].Transactions of Materials and Heat Treatment,2011,32(8):41-46.
- [9]杨争,田保红,刘勇,等.内氧化制备Cu-Al2O3/(Ce+Y)复合材料薄板带的组织和性能[J].材料热处理学报,2010,31(10):5-9.YANG Zheng,TIAN Bao-hong,LIU Yong,et al.Structure and properties of Cu-Al2O3/(Ce+Y)composite thin-sheet by internal oxidation process[J].Transactions of Materials and Heat Treatment,2010,31(10):5-9.
- [10]SELLARS C M.Modeling microstructural development during hot rolling[J].Mater Sci Techno,1990,16(11):1072-1078.
- [11]Bruni C,Forcellese A,Gabrielli F.Hot workability and models for flow stress of NIMONIC 115 Ni-base super alloy[J].Journal of Materials Processing Technology,2002,125/126:242-247.
- [12]Samantaray D,Mandal S,Phaniraj C,et al.Flow behavior and microstructural evolution during hot deformation of AISI type 316 L(N)austenitic stainless steel[J].Mat Sci&Eng A,2011,528(29-30):8565-8572.
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