退火温度对Ti-50.8Ni-0.1Zr合金的相变、组织和拉伸性能的影响Effects of annealing temperatures on transformation,microstructure and tensile properties of Ti-50.8Ni-0.1Zr alloy
樊勇军,周晓龙,贺志荣,曹建春,曹宇,陈敬超
摘要(Abstract):
用示差扫描热分析仪、光学显微镜和拉伸试验研究了不同退火温度(Ta)对Ti-50.8Ni-0.1Zr合金相变行为、显微组织和拉伸行为的影响。结果表明:Ta=400℃时,合金冷却/加热时的相变类型为A→R→M/M→R→A两阶段可逆相变,而Ta=500℃时,冷却/加热合金正逆转变为A→R→M/M→A,在M逆转变过程中没有出现R相。在Ta为600℃和700℃时,合金冷却/加热时发生A→M/M→A一阶段可逆转变。退火时,合金发生回复、再结晶和晶粒长大3个过程。Ta=350~450℃时,为回复阶段,合金组织为纤维状。Ta=500~600℃时,为再结晶阶段,合金组织由纤维状变为无畸变的等轴晶。Ta=650~700℃时,为晶粒长大过程,显微组织为不均匀的粗大等轴晶。随着Ta的升高,合金抗拉强度在减小,马氏体相变临界应力先增大后减小,Ta较高时伸长率显著增大,600℃以后随着晶粒尺寸增大,伸长率有所下降。
关键词(KeyWords): Ti-50.8Ni-0.1Zr合金;形状记忆合金;退火温度;相变行为;显微组织;拉伸性能
基金项目(Foundation): 金川预研基金(金川201102)
作者(Author): 樊勇军,周晓龙,贺志荣,曹建春,曹宇,陈敬超
DOI: 10.13289/j.issn.1009-6264.2013.s1.009
参考文献(References):
- [1]Farhat Z,Zhang C.On the deformation of superelastic TiNi alloy[J].Tribology Letter,2010,37(2):169-173.
- [2]Kang S B,Yoon K S,Kim J S,et al.In vivo result of porous TiNi shape memory alloy:bone response and growth[J]Material Transaction,2002,43(5):1045-1048.
- [3]王心美,岳珠峰,王亚芳,等.NiTi合金的超弹性力学特性及其应用[M].北京:科学出版社,2009:1-2.
- [4]赵连城,蔡伟,郑玉峰.合金的形状记忆效应与超弹性[M].北京:国防工业出版社,2002:15-290.
- [5]刘曼倩,贺志荣.Ti-Ni-V形状记忆合金及其弹簧的相变和形变特性[J].材料热处理学报,2012,33(1):44-48.LIU Man-qian,HE Zhi-rong.Transformation and deformation characteristics of Ti-Ni-V shape memory alloy and spring[J].Transactions of Materailsand Heat Treatment,2012,33(1):44-48.
- [6]贺志荣,王启,王芳,等.退火温度对Ti-Ni-Cr低温超弹性合金组织和拉伸性能的影响[J].稀有金属材料与工程,2011,40(11):1998-2000.HE Zhi-rong,WANG Qi,WANG Fang,et al.Effects of annealing temperatures on microstructure and tensile properties ofTi-Ni-Cr Low-Temperaturesuperelastic alloy[J].Rare Metal Materials and Engineering,2011,40(11):1998-2000.
- [7]Khalil-Allafi J,Eggeler G,Dlouhy A,et al.On the influence of heterogeneous precipitation on martensitic transformations in a Ni-rich NiTi shapememory alloy[J].Material Science and Engineering,2004,378(1-2):148-151.
- [8]刘艳,贺志荣,王芳,等.T i-50.8N i合金的相变、形状记忆和超弹性特性[J].稀有金属材料与工程,2011,40(8):1412-1416.LIU Yan,HE Zhirong,WANG Fang,et al.Transformation,shape memory and superelasticity characteristics of Ti-50.8Ni Alloy[J].Rare MetalMaterials and Engineering,2011,40(8):1412-1416.
- [9]Shozo Inoue,Naoki Sauada,Takahiro Namazu.Effect of Zr content on mechanical properties of Ti-Ni-Zr shape memory alloy films prepared by dcmagnetron sputtering[J].Vacuum,2009,83(3):664-667.
- [10]Hee Young Kim,Masashi Mizutani,Shuichi Miyazaki.Crystallization process and shape memory properties of Ti-Ni-Zr thin films[J].Acta Materialia,2009,57(6):1920-1930.
- [11]Guillermo Bozzolo,Ronald D Noebe,Hugo O Mosca.Site preference of ternary alloying addition to NiTi:Fe,Pt,Pd,Au,Al,Cu,Zr,and Hf[J].Journalof Alloys and Compounds,2005,389(1-2):80-94.
- [12]Teragama A,Nagai K,Kyogoka H.Fabrication of Ti-Ni-Zr shape memory alloy by P/M process[J].Materails Transactions,2009,50(10):2446-2450.
- [13]Clemens H,Fu C L,Inui H,et al.Factors for controlling martensitic transformation temperature of TiNi shape memory alloy by addition of ternaryelements[J].MRS Proceedings,2004,842:353-358.
- [14]Mi-Seon Choi,Jumpei Ogawa,Takashi Fukuda,et al.Stability of the B2-type structure and R-phase transformation behavior of Fe or Co doped Ti-Nialloys[J].Material Science and Engeneering,2006,438-440:527-530.
- [15]蔡继峰,贺志荣,刘曼倩,等.退火工艺对Ti-Ni-Co形状记忆合金组织性能的影响[J].材料热处理学报,2010,31(8):20-24.CAI Ji-feng,HE Zhi-rong,LIU Man-qian,et al.Effect of annealing processes on microstructure and properties of Ti-Ni-Co shape memory alloy[J].Transactions of Materails and Heat Treatment,2010,31(8):20-24.
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