加热温度对Ti微合金化低碳钢中针状铁素体形成的影响Effect of heating temperature on acicular ferrite formation in Ti microalloyed low carbon steel
刘方策,王杨,孔祥磊,刘干,黄明浩
摘要(Abstract):
使用光学显微镜、扫描电镜、电子探针和透射电镜对不同加热温度下Ti微合金化低碳钢的微观组织和夹杂物特征进行了研究。结果表明:随着加热温度由1050℃升高至1320℃,原始奥氏体晶粒尺寸从20μm增大至129μm,针状铁素体的体积分数先增加后减少,在1250℃时达到最大值51%;Ti微合金化钢中复合夹杂物的核心为Ti_2O_3,MnS在Ti_2O_3的表面上沿特定的晶面和晶向析出,夹杂物能够有效地促进针状铁素体形核;针状铁素体的形成能够分割原始奥氏体晶粒、细化组织,因此在1250℃的加热条件下Ti微合金化钢具有最小的有效晶粒尺寸;随着加热温度的升高,总体夹杂物的数量密度减少、平均尺寸增大,然而有效夹杂物的数量密度先增加后减少;结合针状铁素体体积分数和有效夹杂物数量密度的变化规律,1250℃为Ti微合金化钢有利于针状铁素体形成的最佳温度。
关键词(KeyWords): 加热温度;Ti微合金化;针状铁素体;夹杂物
基金项目(Foundation):
作者(Author): 刘方策,王杨,孔祥磊,刘干,黄明浩
DOI: 10.13289/j.issn.1009-6264.2025-0005
参考文献(References):
- [1] Ricks R A,Howell P R,Barritte G S.The nature of acicular ferrite in HSLA steel weld metals[J].Journal of Materials Science,1982,17(3):732-740.
- [2] Li X B,Min Y,Liu C J,et al.Study on the formation of intragranular acicular ferrite in a Zr-Mg-Al deoxidized low carbon steel[J].Steel Research International,2016,87(5):622-632.
- [3] Chai F,Su H,Yang C F,et al.Nucleation behavior analysis of intragranular acicular ferrite in a Ti-killed C-Mn steel[J].Journal of Iron and Steel Research International,2014,21(3):369-374.
- [4] Jia X,Yang Y L,Ma Y X,et al.Effect of different strains on acicular ferrite and martensite-austenite islands in oxide metallurgy steel[J].Journal of Materials Research and Technology,2022,19:1777-1788.
- [5] 王恒辉,万响亮,李光强,等.低合金高强度钢焊缝针状铁素体联锁组织与性能[J].材料热处理学报,2014,35(12):114-120.WANG Heng-hui,WAN Xiang-liang,LI Guang-qiang,et al.Interlocked microstructure of acicular ferrite and properties of high strength low alloy steel weld metal[J].Transactions of Materials and Heat Treatment,2014,35(12):114-120.
- [6] Qi X N,Di H S,Wang X N,et al.Effect of secondary peak temperature on microstructure and toughness in ICCGHAZ of laser-arc hybrid welded X100 pipeline steel joints[J].Journal of Materials Research and Technology,2020,9(4):7838-7849.
- [7] Pan X Q,Yang J,Zhang Y H.Microstructure and fracture characteristics of heat-affected zone in shipbuilding steel plates with Mg deoxidation after high heat input welding[J].Steel Research International,2021,92(11):2100376.
- [8] Xiong Z H,Liu S L,Wang X M,et al.The contribution of intragranular acicular ferrite microstructural constituent on impact toughness and impeding crack initiation and propagation in the heat-affected zone (HAZ) of low C-Mn steels[J].Materials Science and Engineering A,2015,636:117-123.
- [9] Wang X,Chen Y,Wang C,et al.Effect of heat input on microstructure and impact toughness of coarse-grained heat-affected zone in Al-Ca and Ti-Ca killed steels[J].Steel Research International,2020,91(9):200133.
- [10] Qi X N,Wang X N,Di H S,et al.Effect of Ti content on the inclusions,microstructure and fracture mechanism of X100 pipeline steel laser-MAG hybrid welds[J].Materials Science and Engineering A,2022,831:142207.
- [11] Zou X D,Sun J C,Matsuura H,et al.In situ observation of the nucleation and growth of ferrite laths in the heat-affected zone of EH36-Mg shipbuilding steel subjected to different heat inputs[J].Metallurgical and Materials Transactions B,2018,49(5):2168-2173.
- [12] Zhang C J,Gao L N,Zhu L G.Effect of inclusion size and type on the nucleation of acicular ferrite in high strength ship plate steel[J].ISIJ International,2018,58(5):965-969.
- [13] Wang B X,Liu X H,Wang G D.Inclusion characteristics and acicular ferrite nucleation in Ti-containing weld metals of X80 pipeline steel[J].Metallurgical and Materials Transactions A,2018,49(6):2124-2138.
- [14] Seo K,Kim Y,Evans G M,et al.Formation of Mn-depleted zone in Ti-containing weld metals[J].Welding in the World,2015,59(3):373-380.
- [15] Jia X,Chen Y P,Li H K,et al.Study on the mechanism of AF nucleation induced by complex oxide inclusions after LF refining in oxide metallurgical steel[J].Materials Characterization,2023,204:113239.
- [16] Shim J H,Cho Y W,Chung S H,et al.Nucleation of intragranular ferrite at Ti2O3 particle in low carbon steel[J].Acta Materialia,1999,47(9):2751-2760.
- [17] Cheng L,Xu C,Lu L L,et al.Experimental and first principle calculation study on titanium,zirconium and aluminum oxides in promoting ferrite nucleation[J].Journal of Alloys and Compounds,2018,742:112-122.
- [18] 姚浩,刘承军,张立峰.奥氏体化温度对Ti-Zr处理钢中针状铁素体转变的影响[J].工程科学学报,2023,45(6):907-914.YAO Hao,LIU Cheng-jun,ZHANG Li-feng.Effect of austenite grain size on the acicular ferrite transformation in Ti-Zr treated steel[J].Chinese Journal of Engineering,2023,45(6):907-914.
- [19] Lee J L,Pan Y T.The formation of intragranular acicular ferrite in simulated heat-affected zone[J].ISIJ International,1995,35(8):1027-1033.
- [20] Babu S S.The mechanism of acicular ferrite in weld deposits[J].Current Opinion in Solid State and Materials Science,2004,8(3/4):267-278.
- [21] Xiong Z,Liu S,Wang X,et al.Relationship between crystallographic structure of the Ti2O3/MnS complex inclusion and microstructure in the heat-affected zone (HAZ) in steel processed by oxide metallurgy route and impact toughness[J].Materials Characterization,2015,106:232-239.
- [22] Wang X,Wang C,Kang J,et al.An in-situ microscopy study on nucleation and growth of acicular ferrite in Ti-Ca-Zr deoxidized low C-Mn steel[J].Materials Characterization,2020,165:110381.
- [23] Liu F C,Bi Y,Wang C,et al.Inclusion characteristics and acicular ferrite formation in the simulated heat-affected zone of Ti-Zr-killed low-carbon steel[J].Metals and Materials International,2023,29(3):715-729.
- [24] Yang Y K,Zhan D P,Lei H,et al.Coupling effect of prior austenite grain size and inclusion characteristics on acicular ferrite formation in Ti-Zr deoxidized low carbon steel[J].Metallurgical and Materials Transactions B,2020,51(2):480-491.
- [25] Wang C,Wang X,Kang J,et al.Effect of austenitization conditions on the transformation behavior of low carbon steel containing Ti-Ca oxide particles[J].Materials,2019,12(7):1070.
- [26] Liu F C,Li M,Bi Y,et al.Acicular ferrite formation and Mn-depletion behavior around the inclusions in Ti-Mg oxide metallurgy steel with different holding times[J].Materials Today Communications,2023,37:107210.
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