易切削非调质钢凝固过程及钢中MnS析出规律Solidification process and sulfide precipitation behavior in free-cutting non-quenched and tempered steel
李梦龙,王福明,陶素芬,李天生,孟庆勇
摘要(Abstract):
利用Thermo-Calc热力学软件计算研究YF45MnV钢中MnS的平衡析出规律及凝固过程中各元素的偏析行为对MnS析出的影响。结果表明:MnS平衡初始析出温度为1421℃,初始析出温度随C、Si、Al含量增加而降低,随Mn、S含量增加而升高;Scheil凝固过程中,计算得到Mn、S的平衡分配系数分别为0.70、0.02,二者随着凝固过程进行在剩余液相中不断偏析富集,达到平衡浓度积后析出MnS。真空感应炉冶炼不同S含量(0.025%~0.065%)的实验钢,发现钢中硫化物主要为大量细小II类MnS+少量尺寸较大的III类MnS。随S含量的提高,大尺寸MnS数量增加,沿晶界偏聚分布的情况更为严重。
关键词(KeyWords): 易切削非调质钢;Thermo-Calc;MnS;Scheil-Gulliver凝固模型;偏析
基金项目(Foundation): 国家自然科学基金资助项目(51174020);; 中央高校基本科研业务费专项资金(FRF-SD-12-010A)
作者(Author): 李梦龙,王福明,陶素芬,李天生,孟庆勇
DOI: 10.13289/j.issn.1009-6264.2014.04.016
参考文献(References):
- [1]Stuart H.The properties and processing of microalloyed HSLA steels[J].JOM Journal of the Minerals,Metals and Materials Society,1991,43(1):35-40.
- [2]Eng J R P M.Developments in HSLA steel products[J].JOM Journal of the Minerals,Metals and Materials Society,1991,43(1):41-44.
- [3]常开地,王萍,刘卫萍.非调质钢的发展现状和应用进展[J].金属热处理,2011,36(3):80-85.CHANG Kai-di,WANG Ping,LIU Wei-ping.Development status and application prospect of non-quenched tempered steel[J].Heat Treatment of Metals,2011,36(3):80-85.
- [4]董应虎,张英建,魏晓晓,等.控轧控冷工艺对F40MnV非调质钢组织及性能的影响[J].材料热处理学报,2012,33(7):94-99.DONG Ying-hu,ZHANG Ying-jian,WEI Xiao-xiao,et al.Effect of thermo mechanical control process on microstructure and properties of a nonquenched and tempered steel[J].Transactions of Materials and Heat Treatment,2012,33(7):94-99.
- [5]Hosseini S B,Temmel C,Karlsson B,et al.An in-situ scanning electron microscopy study of the bonding between MnS inclusions and the matrix during tensile deformation of hot-rolled steels[J].Metallurgical and Materials Transactions A,2007,38(5):982-989.
- [6]Sims C E.The nonmetallic constituents of steel[J].Transactions of the Metallurgical Society of AIME,1959,215:367-391.
- [7]Tsunekage N,Tsubakino H.Effects of sulfur content and sulfide-forming elements addition on impact properties of ferrite-pearlitic microalloyed steels[J].ISIJ International,2001,41(5):498-505.
- [8]Oikawa K,Ohtani H,Ishida K,et al.The control of the morphology of MnS inclusions in steel during solidification[J].ISIJ International,1995,35(4):402-408.
- [9]王安东,刘国权,杨才福,等.C和N含量对V-N-Ti微合金非调质钢组织的影响[J].材料热处理学报,2007,28(5):51-56.WANG An-dong,LIU Guo-quan,YANG Cai-fu,et al.Effect of carbon and nitrogen content on microstructure of V-N-Ti microalloyed steel[J].Transactions of Materials and Heat Treatment,2007,28(5):51-56.
- [10]Sundman B,Jansson B,Andersson J O.The thermo-calc databank system[J].Calphad,1985,9(2):153-190.
- [11]Chen Q,Sundman B.Computation of partial equilibrium solidification with complete interstitial and negligible substitutional solute back diffusion[J].Materials Transactions,2002,43(3):551-559.
- [12]Won Y M,Thomas B G.Simple model of microsegregation during solidification of steels[J].Metallurgical and Materials Transactions A,2001,32(7):1755-1767.
- [13]Suzuki M,Yamaguchi R,Murakami K,et al.Inclusion particle growth during solidification of stainless steel[J].ISIJ International,2001,41(3):247-256.
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