短时退火对挤压态Mg-6Sn-3Al-1Zn合金组织和性能的影响Effect of short-term annealing on microstructure and properties of extruded Mg-6Sn-3Al-1Zn alloy
朱慧慧,魏福安,丁勇,李芝兰,马鸿斌
摘要(Abstract):
首先以20∶1的挤压比在300℃下对Mg-6Sn-3Al-1Zn合金进行挤压,随后在350℃短时间退火2、5和10 min。采用X射线衍射仪(XRD)、扫描电镜(SEM)、电子背散射衍射(EBSD)和万能试验机等研究了退火后合金的微观组织和力学性能。结果表明:随着退火时间的增加,合金中的Mg_2Sn析出相的数量先增加后趋于稳定,合金的平均晶粒尺寸和{0001}基面织构先增大后减少;当退火时间为5 min时,一方面,Mg_2Sn析出相数量增多,分布更加弥散,并且{0001}基面织构最强,会导致合金的强度上升,但另一方面,平均晶粒尺寸的增加会导致合金的强度降低,这导致合金的屈服强度变化不大;合金的屈服强度从退火2 min时的218 MPa提高到退火5 min时的251 MPa,这说明多峰组织合金中大小晶粒的体积分数对合金的屈服强度影响较大;当退火时间为5 min时,合金中的小晶粒(<10μm)所占体积分数约为80%,中等尺寸晶粒(10~15μm)所占体积分数约为16%,大晶粒(>15μm)所占体积分数约为4%,此时,合金的综合力学性能达到最优,抗拉强度、屈服强度和伸长率分别为372 MPa、251 MPa和17.1%。
关键词(KeyWords): Mg-6Sn-3Al-1Zn合金;退火时间;多峰组织;力学性能
基金项目(Foundation): 青海省应用基础研究项目(2022-ZJ-709)
作者(Author): 朱慧慧,魏福安,丁勇,李芝兰,马鸿斌
DOI: 10.13289/j.issn.1009-6264.2024-0472
参考文献(References):
- [1] Bai J Y,Yang Y,Wen C,et al.Applications of magnesium alloys for aerospace:A review[J].Journal of Magnesium and Alloys,2023,11(10):3609-3619.
- [2] 王凌浩,杨斌,伍先明,等.变形参数对挤压态AZ41M镁合金热变形行为和组织演变的影响[J].材料热处理学报,2021,42(1):50-57.WANG Ling-hao,YANG Bin,WU Xian-ming,et al.Effect of deformation parameters on thermal deformation behavior and microstructure evolution of extruded AZ41M magnesium alloy[J].Transactions of Materials and Heat Treatment,2021,42(1):50-57.
- [3] Dong S Y,Wang Y Y,Li J Y,et al.Machine learning aided prediction and design for the mechanical properties of magnesium alloys[J].Metals and Materials International,2023,30(3):593-606.
- [4] 马鸿斌,魏福安,孙领兄.热处理对Mg-2Nd-xZn合金耐腐蚀性能的影响[J].材料热处理学报,2023,44(5):76-85.MA Hong-bin,WEI Fu-an,SUN Ling-xiong.Effect of heat treatment on corrosion resistance of Mg 2Nd-xZn alloys[J].Transactions of Materials and Heat Treatment,2023,44(5):76-85.
- [5] Li S,Wang Z,Zhao X,et al.Study on the plasticity improvement mechanism and grain refinement of AZ80 Mg alloy under cryogenic multi-directional forging[J].Journal of Materials Research and Technology,2024,33:384-397.
- [6] Lakshmanan A,Andani M T,Yaghoobi M,et al.A combined experimental and crystal plasticity study of grain size effects in magnesium alloys[J].Journal of Magnesium and Alloys,2023,11(12):4445-4467.
- [7] Zhao L,Yan H,Chen J,et al.High ductility and strong work-hardening behavior of Zn modified as-hot-rolled Al-Mg sheets[J].Journal of Alloys and Compounds,2021,854:157079.
- [8] Elsayed F R,Sasaki T T,Mendis C L,et al.Compositional optimization of Mg-Sn-Al alloys for higher age hardening response[J].Materials Science and Engineering A,2013,566:22-29.
- [9] Zhang C,Liang C,Mu J,et al.Study on the work-hardening behavior and tissue property analysis of high-strength magnesium alloy[J].Applied Mathematics and Nonlinear Sciences,2024,9(1):20230432.
- [10] Zhang W,Peng W,Hu H,et al.Deformation behaviour,microstructure evolution and dynamic recrystallization mechanism of AZ31 magnesium alloy under co-extruded by Mg-Al composite billet[J].Materials Today Communications,2023,37:107435.
- [11] Chen W,Liu Y,Gong C,et al.Achieving excellent oxidation resistance in a Mg alloy by grain boundary adhesion and in-situ phase transformation[J].Journal of Materials Research and Technology,2024,30:9205-9212.
- [12] Xu R Z,Ni D R,Yang Q,et al.Influence of Zn interlayer addition on microstructure and mechanical properties of friction stir welded AZ31 Mg alloy[J].Journal of Materials Science,2015,50(12):4160-4173.
- [13] 李明照,范晋平.真空熔炼时AZ31中Mg,Zn挥发行为及组织与性能[J].中北大学学报(自然科学版),2007,28(5):462-466.LI Ming-zhao,FAN Jin-ping.Volatilization behavior and microstructure,properties of Mg,Zn in AZ31during vacuum melt[J].Journal of North University of China (Natural Science Edition),2007,28(5):462-466.
- [14] Manwatkar A A,Deshmukh P B,Setia S,et al.Effect of solutionising on change in phase morphology,mechanical behavior & corrosion behavior for AZ series as cast automotive magnesium alloy components[J].SAE International Journal of Advances and Current Practices in Mobility,2022,5(4):1544-1559.
- [15] Ma H,Meng F Z,Yang Q,et al.Microstructures and mechanical properties of a commercial Mg-Al-Zn-Mn alloy with various hot-extrusion processes[J].Rare Metals,2024,43(3):1329-1336.
- [16] 王润,胡耀波,张琴,等.Sn对Mg-6Zn-3Al合金微观组织和力学性能的影响[J].材料热处理学报,2020,41(9):76-82.WANG Run,HU Yao-bo,ZHANG Qin,et al.Effect of Sn on microstructure and mechanical properties of Mg-6Zn-3Al alloys[J].Transactions of Materials and Heat Treatment,2020,41(9):76-82.
- [17] 张贇龙,刘六法,卫中山,等.合金元素对镁合金耐热性能的优化作用及机理[J].铸造技术,2005(8):697-700.ZHANG Yun-long,LIU Liu-fa,WEI Zhong-shan,et al.Effects of alloying elements on heat-resistant properties of magnesium alloys[J].Foundry Technology,2005(8):697-700.
- [18] Yang C,Li Z,Bao S,et al.High-strength and high-plasticity ZK60 magnesium alloy prepared by rapid solidification and high-speed extrusion[J].Materials Today Communications,2024,41:110570.
- [19] Meng S,Xiao H,Song J,et al.Research progress and future prospects on high speed extrudable magnesium alloys:A review[J].Journal of Materials Research and Technology,2024,30:9007-9019.
- [20] Wei F A,Zhou S H,Wang J H,et al.Effect of extrusion temperature on microstructure,mechanical properties and corrosion resistance of Mg-6Sn-3Al-1Zn alloy[J].Materials Today Communications,2023,37:107328.
- [21] Zhou S H,Wei F A,Wang J H,et al.Effect of extrusion ratio on microstructure and mechanical properties of Mg-6Sn-3Al-1Zn alloy[J].Materials Research Express,2022(9):096517.
- [22] 郑晶,王轶,马光,等.合金组元对Mg-Al-Zn系变形镁合金组织与力学性能的影响[J].钛工业进展,2008,25(5):23-27.ZHENG Jing,WANG Yi,MA Guang,et al.Effect of components on microstructure and mechanical properties of Mg-Al-Zn wrought magnesium alloys[J].Titanium Industry Progress,2008,25(5):23-27.
- [23] Zhang Y,Wang Z,Li S,et al.High strength and excellent ductility of AZ80 magnesium alloy cabin component developed by w-shaped channel extrusion and subsequent t6 heat treatment[J].Acta Metallurgica Sinica (English Letters),2023,36(5):839-856.
- [24] Barylski A,Anio?ek K,Dercz G,et al.The effect of changes in the aging temperature combined with deep cryogenic treatment on the structure,phase composition,and micromechanical properties of the WE43 magnesium alloy[J].Materials,2023,16(23):7447.
- [25] Wei F A,Wang J H,Shi B,et al.Effect of annealing time on bimodal microstructures and tensile properties of Mg-6Sn-3Al-1Zn alloy[J].Materials Research Express,2020(7):1-12.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||