快速凝固Mg80Cu10Y10金属玻璃的晶化行为Crystallization behavior of rapidly solidified of Mg80Cu10Y10 metallic glass
宁向梅,黄金亮,殷镖,张兴渊
摘要(Abstract):
采用单辊快速凝固法制备了Mg80Cu10Y10合金薄带,并对合金薄带进行热处理,利用XRD、DSC和HRTEM分析研究了该合金薄带的晶化过程及其晶化后的微观结构。结果表明:快速凝固Mg80Cu10Y10合金薄带为单一的非晶态结构,其约化玻璃转变温度Trg为0.62,具有较强的非晶形成能力;非晶合金具有三阶段晶化行为;在热处理温度为423 K时合金仍为非晶态;当温度达到473 K时,合金发生明显晶化,在非晶基体上弥散析出Mg2Cu、Cu2Y和hcp-Mg纳米晶粒;随着温度由523 K升高至623 K时,析出晶粒尺寸增大、数目减少,合金中的晶体相为hcp-Mg、Mg2Cu和Mg24Y5。
关键词(KeyWords): 快速凝固;Mg80Cu10Y10;金属玻璃;非晶形成能力;晶化
基金项目(Foundation): 河南科技大学青年科学研究基金项目(2006QN028);; 河南省杰出青年基金项目(074100510008)
作者(Author): 宁向梅,黄金亮,殷镖,张兴渊
DOI: 10.13289/j.issn.1009-6264.2013.04.007
参考文献(References):
- [1]陈振华,严红革,陈吉华,等.镁合金[M].北京:化学工业出版社,2004:19-20.
- [2]肖冬飞,谭敦强,欧阳高勋,等.镁合金快速凝固技术的研究现状及进展[J].铸造,2007,56(9):909-913.XIAO Dong-fei,TAN Dun-qiang,OUYANG Gao-xun,et al.Current status and development of rapidly solidified magnesium alloys[J].Foundry,2007,56(9):909-913.
- [3]黄正华,郭学锋,张忠明.快速凝固AZ91D镁合金组织的研究[J].材料热处理学报,2005,26(1):32-35.HUANG Zheng-hua,GUO Xue-feng,ZHANG Zhong-ming.Study on microstructures of rapidly solidified AZ91D magnesium alloy[J].Transactions ofMaterials and Heat Treatment,2005,26(1):32-35.
- [4]孙国元,陈光.Mg65Cu25Y10大块金属玻璃的玻璃转变行为与玻璃形成能力[J].材料科学与工程学报,2004,22(1):142-145.SUN Guo-yuan,CHEN Guang.Glass transition behavior and glass-forming ability of Mg65Cu25Y10 bulk metallic Glasses[J].Journal of MaterialsScience&Engineering,2004,22(1):142-145.
- [5]孙国元,陈光,刘平.Mg65Cu25Y10大块非晶合金的晶化行为研究进展[J].兵器材料科学与工程,2004,27(4):62-67.SUN Guo-yuan,CHEN Guang,LIU Ping.Research progress of crystallization behavior of bulk amorphous Mg65Cu25Y10 alloy[J].Ordnance MaterialScience and Engineering,2004,27(4):62-67.
- [6]杨春秀,王晓军,陈学定,等.Mg-Al-Cu-Y大块非晶合金的玻璃形成能力[J].兰州理工大学学报,2005,31(2):13-15.YANG Chun-xiu,WANG Xiao-jun,CHEN Xue-ding,et al.Glass forming ability of bulk amorphous Mg-Al-Cu-Y alloys[J].Journal of LanzhouUniversity of Technology,2005,31(2):13-15.
- [7]黎业生,吴子平,董定乾,等.Mg65Cu25Y10非晶态合金的形成及其晶化行为[J].材料热处理学报,2006,27(2):20-23.LI Ye-sheng,WU Zi-ping,DONG ding-qian,et al.Formation and crystallized behavior of Mg65Cu25Y10 amorphous alloy[J].Transactions of Materialsand Heat Treatment,2006,27(2):20-23.
- [8]Hojvat de Tendler R,Soriano M R,Pepe M E,et al.Calculation of metastable free-energy diagrams and glass formation in the Mg-Cu-Y alloy and itsboundary binaries using the Miedema model[J].Intermetallics,2006,14(3):297-307.
- [9]Geun Tae Bae,Sang Bok Lee,Nack J Kim.Effect of alloying elements on the crystallization kinetics of Mg-Cu-(Y,Gd)bulk amorphous alloys[J].Materials Science and Engineering A,2007,449-451:489-492.
- [10]Cheng Y T,Hung T H,Huang J C,et al.Effects of partial replacement of Cu and Y by B in Mg-Cu-Y amorphous alloys[J].Intermetallics,2006,14(8-9):866-870.
- [11]Deok Kim,Byeong Joo Lee,Nack J Kim.Prediction of composition dependency of glass forming ability of Mg-Cu-Y alloys by thermodynamic approach[J].Scripta Materialia,2005,52(10):969-972.
- [12]Cheng Y T,Hung T H,Huang J C,et al.Thermal stability and crystallization kinetics of Mg-Cu-Y-B quaternary alloys[J].Materials Science andEngineering A,2007,449-451:501-505.
- [13]高玉来,沈军,孙剑飞,等.快速凝固粉末冶金技术制备大块非晶材料[J].特种铸造及有色合金,2003,24(4):27-29.GAO Yu-lai,SHEN Jun,SUN Jian-fei,et al.Preparation of bulk amorphous alloy with high property in rapidly solidified powder metallurgy[J].Special Casting&Nonferrous Alloys,2003,24(4):27-29.
- [14]Inoue A,Zhang T,Takeuchi A.Ferrous and nonferrous bulk amorphous alloys[J].Materials Science Forum,1997,269-272:855-864.
- [15]Young Kwan Kim,Jeong Ryong Soh,Do Kyung Kim,et al.Glass formation in metallic Al-Ni-Y[J].Journal of Non-Crystalline Solids,1998,242(2-3):122-130.
- [16]闫志杰,柴跃生.大块非晶合金[M].北京:兵器工业出版社,2005:31-33.
- [17]吴树森,刘伟,毛有武,等.Nd对块体Mg-Cu-Y-Nd非晶合金玻璃形成能力的影响[J].中国有色金属学报,2007,17(6):852-857.WU Shu-sen,LIU Wei,MAO You-wu,et al.Effect of Nd on glass forming ability of bulk amorphous Mg-Cu-Y-Nd alloys[J].The Chinese Journal ofNonferrous Metals,2007,17(6):852-857.
- [18]卢博斯基F E.非晶态金属合金[M].柯成,唐于谌,罗阳,等译.北京:冶金工业出版社,1989:192-216.
- [19]Xing L Q,Eckert J,Loser W,et al.Crystallization behaviour and nanocrystalline microstructure evolution of a Zr57Cu20Al10Ni8Ti5 bulk amorphousalloy[J].Philosophical Magazine A,1999,79(5):1095-1108.
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