钎焊中高温氧化对硬质合金的影响Effect of high temperature oxidation on cemented carbide during brazing
徐登强,李惠琪,李敏,王淑峰,迟静
摘要(Abstract):
研究了YG-11C硬质合金在900、950、1000℃下加热的氧化行为,并测试了在钎焊过程中受氧化的硬质合金刀头性能。结果表明,硬质合金在900℃以上加热10 min发生氧化,硬质相WC和粘结相Co被氧化成WO3和Co WO4;氧化后的硬质合金发生变形及增重,随温度升高,氧化现象更严重,变形增重更明显;高温钎焊后的硬质合金刀头表面氧化后,微观组织变得疏松多孔,硬度及耐磨性明显降低。
关键词(KeyWords): 硬质合金;钎焊;氧化;组织;性能
基金项目(Foundation): 青岛市科技发展计划项目(12-1-4-6-(4)-jch)
作者(Author): 徐登强,李惠琪,李敏,王淑峰,迟静
DOI: 10.13289/j.issn.1009-6264.2015.01.016
参考文献(References):
- [1]孟凡军,徐滨士.高速电弧喷涂Fe-Al/WC复合涂层在800℃下的氧化行为[J].金属热处理,2003,28(12):18-21.MENG Fan-jun,XU Bin-shi.Oxidation behavior of high velocity arc spraying composite coating of Fe-Al/WC under 800℃[J].Heat Treatment of Metals,2003,28(12):18-21.
- [2]黄道远,易丹青.471和3555两种硬质合金的高温氧化行为[J].材料热处理学报,2013,34(2):27-31.HUANG Dao-yuan,YI Dan-qing.High temperature oxidation behavior of 471 and 3555 of two kinds of hard alloy[J].Transactions of Materials and Heat Treatment,2013,34(2):27-31.
- [3]刘寿荣.WC-Co硬质合金的显微结构参数[J].材料热处理学报,2005,26(1):62-64.LIU Shou-rong.Microstructure parameters of WC-Co cemented carbide[J].Transactions of Materials and Heat Treatment,2005,26(1):62-64.
- [4]任鑫,杜学芸.硬质合金高温氧化行为研究[J].热加工工艺,2011,40(10):78-79.REN Xin,DU Xue-yun.Study on cemented carbide of high temperature oxidation behavior[J].Hot Working Technology,2011,40(10):78-79.
- [5]Basu S,Sarin V.Oxidation behavior of WC-Co[J].Materials Science and Engineering A,1996,209(1):206-212.
- [6]Casas B,Ramis X,Anglada M,et al.Oxidation-induced strength degradation of WC-Co hard metals[J].International Journal of Refractory Metals and Hard Materials,2001,19(4):303-309.
- [7]Voitovich V B,Sverdel V V,et al.Oxidation of WC-Co,WC-Ni and WC-Co-Ni hard metals in the temperature range 500~800℃[J].International Journal of Refractory Metals and Hard Materials,1996,14(4):289-295.
- [8]黄道远,易丹青.硬质合金强度随温度的变化及失效机理的研究[J].材料热处理学报,2007,28(5):105-108.HUANG Dao-yuan,YI Dan-qing.Study on variation with temperature and the failure mechanism of cemented carbide strength[J].Transactions of Materials and Heat Treatment,2007,28(5):105-108.
- [9]Deng X,Patterson B R,Chaw la K K,et al.Microstructure/hardness relationship in a dual composite[J].Journal of Materials Science Letters,2002,21:707-709.
- [10]宫文彪,杜辉,孙大千.WC颗粒增强Ni基合金涂层的组织与性能[J].金属热处理,2006,31(2):26-29.GONG Wen-biao,DU Hui,SUN Da-qian.Microstructure and properties of WC reinforced Ni based alloy coating[J].Heat Treatment of Metals,2006,31(2):26-29.
- [11]龙震海,王西彬.高速铣削难加工材料时硬质合金刀具前刀面磨损机理及切削性能研究[J].摩擦学学报,2005,25(1):83-87.LONG Zhen-hai,WANG Xi-bin.High speed milling of difficult to machine materialsresearch on wear mechanism and cutting performance of carbide tools[J].Tribology,2005,25(1):83-87.
- [12]赵世贤,宋晓燕,刘雪梅.超细硬质合金显微组织参数与力学性能定量关系的研究[J].金属学报,2011,47(9):1188-1194.ZHAO Shi-xian,SONG Xiao-yan,LIU Xue-mei.Study on the quantitative relationship between parameters and mechanical properties of microstructure of ultrafine cemented carbide[J].Acta Metaiiurgica Sinica,2011,47(9):1188-1194.
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