阳极氧化工艺对6061铝合金草酸氧化膜耐磨耐蚀性的影响Effect of anodizing process on corrosion and wear resistance of 6061 alloy anodic oxide films formed in oxalic acid
刘莉,张鲲,熊辉辉,宁淑红,胡琪,董立新,陈辉
摘要(Abstract):
为改善6061铝合金的表面耐磨性能和耐蚀性能,利用阳极氧化技术在草酸电解液中制备了阳极氧化膜。采用显微硬度仪测试了膜层的显微硬度,利用摩擦磨损试验机(CSEM)研究阳极氧化膜的摩擦性能,利用电化学阻抗谱(EIS)分析氧化膜的抗腐蚀性能。研究了阳极氧化电流密度、电解液温度以及阳极氧化时间对氧化膜的硬度、耐磨性及耐蚀性的影响规律,给出综合性能较好的阳极氧化工艺参数:电解液为40 g·L-1的草酸,阳极氧化温度为10℃,阳极氧化电流密度为1.0 A·dm-2,阳极氧化时间为120 min。
关键词(KeyWords): 阳极氧化;草酸;耐磨;耐蚀;电化学阻抗
基金项目(Foundation): 国家自然科学基金(51201144);; 中国博士后科学基金(2013M542288);; 中国科学院无机特种涂层重点实验室开放基金(KLICM-2012-08)
作者(Author): 刘莉,张鲲,熊辉辉,宁淑红,胡琪,董立新,陈辉
DOI: 10.13289/j.issn.1009-6264.2015.11.038
参考文献(References):
- [1]黄元盛,陈焕明.6063铝合金的大电流密度间歇式阳极氧化[J].金属热处理,2014,39(1):117-119.HUANG Yuan-sheng,CHEN Huan-ming.Anodic oxidation of 6063 aluminum alloy with intermittent high current density[J].Heat Treatment of Metals,2014,39(1):117-119.
- [2]白新德,陈鹤鸣,马春来,等.草酸溶液中铝池壳的阳极氧化技术[J].稀有金属材料与工程,2004,33(3):300-304.BAI Xin-de,CHEN He-ming,MA Chun-lai,et al.Technology of anodization of aluminum pool shell for nuclear reactor in oxalic acid solution[J].Rare Metal Material and Engineering,2004,33(3):300-304.
- [3]Vrublevsky I,Parkoun V,Schreckenbach J,et al.Study of porous oxide film growth on aluminum in oxalic acid using a re-anodizing technique[J].Applied Surface Science,2004,227(1):282-292.
- [4]Zaraska L,Stpniowski W J,Sulka G D,et al.Analysis of nanopore arrangement and structural features of anodic alumina layers formed by two-step anodizing in oxalic acid using the dedicated executable software[J].Applied Physics A,2014,114(2):571-577.
- [5]Sulka G D,Stpniowski W J.Structural features of self-organized nanopore arrays formed by anodization of aluminum in oxalic acid at relatively high temperatures[J].Electrochimica Acta,2009,54(14):3683-3691.
- [6]薛守迪,杨成韬,孟璐璐.LY12铝合金表面阳极氧化膜的制备,分析及耐磨性[J].材料保护,2010,43(12):8-10.XUE Shou-di,YANG Cheng-tao,MENG Lu-lu.Preparation,analysis and abrasion resistance of LY12 aluminum anodized surface film[J].Journal of Materials Protection,2010,43(12):8-10.
- [7]LEE W,Ji R,G sele U,et al.Fast fabrication of long-range ordered porous alumina membranes by hard anodization[J].Nature Materials,2006,5(9):741-747.
- [8]徐洮,陈建敏,赵家政.多孔质铝阳极氧化膜的结构及其摩擦学性能研究[J].摩擦学学报,1996,16(2):97-104.XU Tao,CHEN Jian-min,ZHAO Jia-zheng.Study on the porous structure and tribological properties of anodic oxide films of aluminum[J].Tribology,1996,16(2):97-104.
- [9]Lopez V,Otero E,Bautista A,et al.Sealing of anodic films obtained in oxalic acid baths[J].Surface and Coatings Technology,2000,124(1):76-84.
- [10]Hitzig J,Jüttner K,Lorenz W J,et al.AC-impedance measurements on corroded porous aluminum oxide films[J].Journal of the Electrochemical Society,1986,133(5):887-892.
- [11]李重阳,刘道新,叶作彦,等.微弧氧化与稀土铈盐封孔对7A85新型铝合金耐蚀和耐磨性能的影响[J].机械科学与技术,2014,33(1):127-132.LI Chong-yang,LIU Dao-xin,YE Zuo-yan,et al.Effect of the micro-arc oxidation and cerium salt sealing on the corrosion and wear resistance of new7A85[J].Mechanical Science and Technology for Aerospace Engineering,2014,33(1):127-132.
- [12]Bensalah W,Elleuch K,Feki M,et al.Comparative study of mechanical and tribological properties of alumina coatings formed on aluminium in various conditions[J].Materials&Design,2009,30(9):3731-3737.
- [13]刘建华,高庆娜,于美,等.氧化时间对2A12铝合金阳极氧化膜开裂行为的影响[J].材料热处理学报,2015,36(3):159-164.LIU Jian-hua,GAO Qing-na,YU Mei,et al.Effect of anodizing time on cracking behavior of anodic oxide film of 2A12 alloy[J].Transactions of Materials and Heat Treatment,2015,36(3):159-164.
- [14]Ren J,Zuo Y.The anodizing behavior of aluminum in malonic acid solution and morphology of the anodic films[J].Applied Surface Science,2012,261:193-200.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||