电沉积电位对锌镍合金镀层耐蚀性的影响Effect of electrodeposition potential on corrosion resistance of Zn-Ni alloy coatings
李宏亮,郭汉杰,王晓辉,沈中敏,苏耀,彭学诚,郭佳,曹丽丽,薛彦鹏
摘要(Abstract):
采用电化学沉积方法在DH36船板钢表面制备了锌镍合金镀层。采用扫描电镜(SEM),能谱仪(EDS)和X射线衍射仪(XRD)等研究了电化学沉积电位对锌镍合金镀层形貌、化学成分和晶体结构的影响。结果表明:随着沉积电位的升高,锌镍合金镀层由无法覆盖整个基底表面到均匀致密覆盖,再到较大微纳米颗粒层覆盖,证明沉积速率越来越大。由EDS和XRD分析可知,在较低电位下沉积,锌镍电沉积过程属于正常共沉积,而在较高电位沉积时,锌镍电沉积过程属于异常共沉积。电化学极化曲线测试表明,在电沉积电位为-1.2 V时所获得的锌镍合金镀层的耐腐蚀性最好。
关键词(KeyWords): 船板钢;电沉积;锌镍合金镀层;耐蚀性
基金项目(Foundation):
作者(Author): 李宏亮,郭汉杰,王晓辉,沈中敏,苏耀,彭学诚,郭佳,曹丽丽,薛彦鹏
DOI: 10.13289/j.issn.1009-6264.2019-0486
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