SDCM1新型热作模具钢回火过程中碳扩散行为的电阻表征Characterization of carbon diffusion behaviors of SDCM1 new hot working die steel during tempering by in-situ resistance method
张进峰,吴晓春,闵娜
摘要(Abstract):
采用原位电阻法,并结合硬度测量、微观组织分析技术对SDCM1新型热作模具钢从室温至590℃回火过程中的碳原子扩散行为进行了研究。结果表明:在80℃至125℃回火时,试验钢的电阻偏离线性出现下降趋势,同时硬度出现峰值,这主要是由于碳原子向位错扩散所致,其激活能为83 kJ·mol~(-1);180~250℃回火时,电阻偏离线性略微降低,归因于ε碳化物的形核;300℃以上回火时,电阻随温度升高增势减缓,结合透射电镜(TEM)分析,这主要是由于碳化物的析出所致,通过电阻的不同演化趋势可以判断碳化物和合金碳化物的析出差异;温度升高至590℃等温时,试验钢的电阻急剧下降,这主要是由于等温碳化物的大量析出所致。研究表明电阻法可以清晰表征模具钢的回火过程中碳原子运动、占位及组织演化特征与动力学过程,是一种有效的研究手段。
关键词(KeyWords): 热作模具钢;碳扩散;电阻;偏聚;析出
基金项目(Foundation): 国家重点研发计划(2016YFB0300400);; 苏州市职业大学科研平台(201804000050)
作者(Author): 张进峰,吴晓春,闵娜
DOI: 10.13289/j.issn.1009-6264.2020-0445
参考文献(References):
- [1] 邵严,吴晓春.几种新型热作模具钢的性能对比研究[J].上海金属,2011,33(2):1-4SHAO Yan,WU Xiao-chun.Properties comparison for different new hot working die steels[J].Shanghai Metal,2011,33(2):1-4.
- [2] 黎军顽,周路海,邵严,等.两种新型热作模具钢的高温性能对比[J].机械工程材料,2012,36(12):67-72.LI Jun-wan,ZHOU Lu-hai,SHAO Yan,et al.High temperature property comparison for two new hot working die steels[J].Materials for Mechanical Engineering,2012,36(12):67-72.
- [3] Li S H,Deng L H,Wu X C,et al.Low-frequency internal friction investigating of the carbide precipitation in solid solution during tempering in high alloyed martensitic steel[J].Materials Science and Engineering A,2010,527(26):6899-6903.
- [4] 闵娜,石楠楠,沈赟靓,等.马氏体热作模具钢热稳定性的内耗研究[J].材料热处理学报,2012,33(2):96-99.MIN Na,SHI Nan-nan,SHEN Yun-liang,et al.Internal friction investigation on thermal-stability of martensitic hot work tool steel[J].Transactions of Materials and Heat Treatment,2012,33(2):96-99.
- [5] 黄宇,成国光,鲍道华.H13钢中一次碳化物的特征及控制进展[J].工程科学学报,2020,42(10):1244-1253.HUANG Yu,CHENG Guo-guang,BAO Dao-hua.Current status of the characteristics and control of primary carbides in H13 steel[J].Chinese Journal of Engineering,2020,42(10):1244-1253.
- [6] Zhao X L,Wang B,Sun D J,et al.Effect of pre-existing VC carbides on nitriding and wear behavior of hot-work die steel[J].Applied Surface Science,2019,486:179-186.
- [7] Speich G R.Tempering of low-carbon martensite[J].Trans.TMS-A1ME,1969(245):2553-2564.
- [8] Speer J,Matlock D K,De Cooman B C,et al.Carbon partitioning into austenite after martensite transformation[J].Acta Materialia,2003,51(9):2611-2622.
- [9] Mola J,De Cooman B C.Quenching and partitioning (Q&P) processing of martensitic stainless steels[J].Metallurgical and Materials Transactions A,2013,44(2):946-967.
- [10] Zhang J F,Wu X C,Ding H L.Design and realization of intelligent electrical resistivity measurement system[J].Advanced Materials Research,2014,1039:210-216.
- [11] 王明,谢尘,吴晓春.低温处理对SDC99冷作模具钢组织与耐磨性的影响[J].材料热处理学报,2016,37(6):146-150.WANG Ming,XIE Chen,WU Xiao-chun.Influence of cryogenic treatment on microstructure and wear resistanceof SDC99 cold work die steel[J].Transactions of Materials and Heat Treatment,2016,37(6):146-149.
- [12] 姚忠凯.钢的组织转变:译文集[M].北京:机械工业出版社,1980.YAO Zhong-kai.Microstructure Transformation of Steels[M].Beijing:China Machine Press,1980.
- [13] Yamada Y.Static strain aging of eutectoid carbon steel wires[J].Transactions of the Iron and Steel Institute of Japan,1976,16(8):417-426.
- [14] Harper S.Precipitation of carbon and nitrogen in cold-worked alpha-iron[J].Physical Review,1951,83(4):709-712.
- [15] Jean-Marie R,GèNiN.The clustering and coarsening of carbon multiplets during the aging of martensite from m?ssbauer spectroscopy:theprecipitation stage of epsilon carbide[J].Metallurgical Transactions A,1987(18):1371.
- [16] Chen P C,Winchell P G.Martensite lattice changes during tempering[J].Metallurgical Transactions A,1980(11):1333-1339.
- [17] Cohen M.Symposium on the tempering of steel[J].Metallurgical Transaction A,1983(14):991-993.
- [18] Sherman A M,Eldis G T,Cohen M.The aging and tempering of iron-nickel-carbon martensites[J].Metallurgical Transactions A,1983(14):995-1005.
- [19] Chen R C,Wang Z G,He J G,et al.Effects of rare earth elements on microstructure and mechanical properties of H13 die steel[J].Metals,2020,10(7):918.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||