Y对Cu-Cr-Zr合金高温热变形行为的影响Effects of Y addition on hot deformation behavior of Cu-Cr-Zr alloy at elevated temperature
李瑞卿,田保红,张毅,许倩倩,刘勇
摘要(Abstract):
利用Gleeble-1500D热模拟试验机对Cu-Cr-Zr和Cu-Cr-Zr-Y合金,进行高温等温压缩试验,研究了在变形温度为650~850℃、应变速率为0.001~10 s-1条件下两种合金的流变应力的变化规律,测定了真应力一应变曲线,从流变应力、应变速率和温度的相关性,得出了该合金热压缩变形时的热变形激活能Q和本构方程,并利用光学显微镜分析了合金在热压缩过程中的组织演变及动态再结晶机制。结果表明:稀土元素Y的加入细化了微观组织,提高了Cu-Cr-Zr合金的动态再结晶体积分数,并且大幅降低了合金的热变形激活能Q,改善了其热加工性能。
关键词(KeyWords): Y;Cu-Cr-Zr合金;热压缩变形;热变形激活能;动态再结晶;热加工性能
基金项目(Foundation): 国家自然科学基金(51101052);; 河南省高等学校青年骨干教师资助计划(2012GGJS-073);; 河南省教育厅自然科学研究计划(2011B430013);; 河南科技大学青年科学基金(2011QN48)
作者(Author): 李瑞卿,田保红,张毅,许倩倩,刘勇
DOI: 10.13289/j.issn.1009-6264.2014.04.010
参考文献(References):
- [1]赵冬梅,董企铭,刘平,等.铜合金引线框架材料的发展[J].材料导报,2001,15(5):25-27.ZHAO Dong-mei,DONG Qi-ming,LIU Ping,et al.Development of copper alloys for leadframe[J].Materials Review,2001,15(5):25-27.
- [2]于朝清.引线框架用高强高导铜合金材料[J].电工材料,2005,(2):33-37.2001,15(5):25-27.YU Chao-qing.The summary of copper alloy with high-strength and high-conductivity[J].Electrical Engineering Materal,2005,(2):33-37.
- [3]Batra I S,Day G K,Kulkarni U D,et al.Microstructureand properties of a Cu-Cr-Zr alloy[J].J Nuclear Mater,2001,299(2):91-100.
- [4]Vinogradov A,Patlan V,Suzuki Y,et al.Structure and properties of ultra-fine grain Cu-Cr-Zr alloy[J].Acta Master,2002,50:1639-1651.
- [5]Su Juanhua,Dong Qiming,Liu Ping,et al.Research on aging precipitation in a Cu-Cr-Zr-Mg alloy[J].Mater Sci Eng A,2005,392:422-426.
- [6]Zhang L,Li Z,Lei Q,et al.Hot deformation behavior of Cu-8.0Ni-1.8Si-0.15Mg alloy[J].Materials Science and Engineer A,2011,528(3):1641-1647.
- [7]ZHANG Hui,ZHANG Hong-gang,LI Luo-xing.Hot deformation behavior of Cu-Fe-P alloys during compression at elevated temperatures[J].Journal of Materials Processing Technology,2009,209(6):2892-2896.
- [8]董企铭,苏娟华,刘平,等.Cu-Cr-Zr-Mg合金时效析出研究[J].材料热处理学报,2004,25(3):38-41.DONG Qi-ming,SU Juan-hua,LIU Ping,et al.Research on aging precipitation in a Cu-Cr-Zr-Mg alloy[J].Transactions of Materials and Heat Treatment,2004,25(3):38-41.
- [9]Suzuki H,Kanno M.Some properties of Cu-Cr-Hf alloys[J].J Jpn Inst Metals,1969,33(2):174-178.
- [10]Batawi E,Morris D G,Morris M A.Effect of small alloying additions on behavior of rapidly solidified Cu-Cr alloys[J].Mater Sci Technol,1990,6(9):892-899.
- [11]刘勇,刘平,李伟,等.Cu-Cr-Zr-Y合金时效析出行为研究[J].功能材料,2005,36(3):377-379.LIU Yong,LIU Ping,LI Wei,et al.Aging precipitation behavior of Cu-Cr-Zr-Y alloy[J].Journal of Functional Materials,2005,36(3):377-379.
- [12]孔凡涛,李宝辉,陈玉勇,等.稀土Y对Ti-43Al-9V合金热变形行为的影响[J].稀有金属材料与工程,2005,34(S3):79-81.KONG Fan-tao,LI Bao-hui,CHEN Yu-yong,et al.Effect of rare earth element Y on hot-press deformation behavior of Ti-43Al-9V alloy[J].Rare Metal Materials and Engineering,2005,34(S3):79-81.
- [13]胡赓祥,蔡珣,戎咏华.材料科学基础(第二版)[M].上海:上海交通大学出版社,2009:106-108.
- [14]Garofalo F.An empirical relation refining the stress dependence of minimum creep rate in metals[J].Trans Metall Soc AIME,1963,227(2):351-355.
- [15]Sellars C M,Mctegart W J.On the mechanism of hot deformation[J].Acta Metall,1966,14:1136-1138.
- [16]Zenergy C,Hollomon J H.Effect of strain-rate upon the plastic flow of stell[J].J Appl Phys,1944,15(1):22-27.
- [17]Mcqueen H J,Yue S,Ryan N D.Hot working characteristics of steels in austenitic state[J].Mater Process Technol,1995,53:293-310.
- [18]赵瑞龙,刘勇,田保红,等.纯铜的高温变形行为[J].金属热处理,2011,36(8):16-20.ZHAO Rui-long,LIU Yong,TIAN Bao-hong,et al.High temperature deformation behavior of pure copper[J].Heat Treatment of Metals,2011,36(8):16-20.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||